Chain-tailed dodecahedron structure derived from Zn/Co-ZIFs/CNTs with excellent rate capability as an anode for lithium-ion batteries

被引:6
作者
Fu, Hang [1 ]
Shi, Chonghua [1 ]
Li, Zhitong [1 ]
Nie, Jiajin [1 ]
Yao, Shaowei [1 ,2 ]
机构
[1] North China Univ Sci & Technol, Coll Mat Sci & Engn, Tangshan 063210, Hebei, Peoples R China
[2] Key Lab Inorgan Mat Hebei Prov, Tangshan 063210, Peoples R China
关键词
Zn/Co-ZIFs/CNTs dodecahedron; Electrochemical performance; Lithium-ion batteries; Anode materials; ZEOLITIC IMIDAZOLATE FRAMEWORKS; METAL-ORGANIC FRAMEWORKS; CARBON; PERFORMANCE; SUPERCAPACITOR; NANOCOMPOSITES; INTERCALATION; STABILITY; COMPOSITE; DESIGN;
D O I
10.1016/j.jallcom.2022.164104
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Herein, a unique dodecahedron composite material of Zn-Co bimetallic zeolitic imidazolate frameworks (ZIFs) and carbon nanotubes (CNTs) is synthesized by a simple room temperature static precipitation-annealing process. As an anode material for lithium-ion batteries (LIBs), the designed nanomaterials exhibits excellent lithium storage performance and cycle performance. It demonstrates a high discharge specific capacity of 720.9 mAh g(-1) at 100 mA g(-1). Besides, a high reversible capacity of 608.7 mAh g(-1) at a current density of 500 mA g(-1) after 300 cycles. The significant improvement in the electrochemical performance of Zn/Co-ZIFs/CNTs nanocomposite can be attributed to the strong synergy between Zn/Co-ZIFs and CNTs. (C) 2022 Elsevier B.V. All rights reserved.
引用
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页数:7
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