NiO-Co3O4-rGO as an Efficient Electrode Material for Supercapacitors and Direct Alcoholic Fuel Cells

被引:121
作者
Askari, Mohammad Bagher [1 ]
Salarizadeh, Parisa [2 ]
Beheshti-Marnani, Amirkhosro [3 ]
Di Bartolomeo, Antonio [4 ,5 ]
机构
[1] Univ Guilan, Fac Sci, Dept Phys, POB 41335-1914, Rasht, Iran
[2] Vali E Asr Univ Rafsanjan, High Temp Fuel Cell Res Dept, Rafsanjan 1599637111, Iran
[3] Payame Noor Univ PNU, Dept Chem, Tehran 193954697, Iran
[4] Univ Salerno, Dept Phys ER Caianiello, I-84084 Salerno, Italy
[5] Univ Salerno, Interdept Ctr NANOMATES, I-84084 Salerno, Italy
关键词
Co; O-3; (4); ethanol oxidation; methanol oxidation; NiO; rGO; supercapacitors; TRANSITION-METAL OXIDES; REDUCED GRAPHENE OXIDE; METHANOL OXIDATION; ASSISTED SYNTHESIS; RECENT PROGRESS; PERFORMANCE; NICKEL; NANOSHEETS; COMPOSITE; CATALYSTS;
D O I
10.1002/admi.202100149
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Transition metal oxides can be performant electrode materials for supercapacitors and alcohol oxidation if their conductivity and capacity are improved. Herein, an advanced nanocomposite material made of NiO-Co3O4 on reduced graphene oxide (rGO) is synthesized by a one-step hydrothermal method for supercapacitors and methanol/ethanol oxidation. It is demonstrated that the nanocomposite is a promising material for energy storage as NiO-Co3O4-rGO supercapacitor electrodes achieve a specific capacity of 149 mAh g(-1) (894 F g(-1)) at a current density of 0.5 A g(-1), the discharge time of 689 s, and excellent stability of 95% after 6000 cycles. Moreover, NiO-Co3O4-rGO shows a current density of 15 and 10 mA cm(-2) in methanol and ethanol oxidation reactions, respectively, along with excellent stability.
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页数:10
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