Environmental monitoring study of selected veterinary antibiotics in animal manure and soils in Austria

被引：487

作者：

Martinez-Carballo, Elena ^{[1
]}

Gonzalez-Barreiro, Carmen ^{[1
]}

Scharf, Sigrid ^{[1
]}

Gans, Oliver ^{[1
]}

机构：

[1] Austrian Fed Environm Agcy, Umweltundesamt GmbH, Dept Hazardous Subst & Metabolites, A-1090 Vienna, Austria

来源：

ENVIRONMENTAL POLLUTION | 2007年 / 148卷 / 02期

关键词：

veterinary antibiotics; animal manure; soil; liquid chromatography/tandem mass spectrometry;

D O I：

10.1016/j.envpol.2006.11.035

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

LC-MS/MS was used for determination of selected tetracyclines, sulfonamides, trimethoprim, and fluoroquinolones in manure samples of pig, chicken and turkey, as well as arable soils fertilized with manure. Recoveries from spiked samples ranged from 61 to 105%. Method quantification limits were set to 100 mu g/kg for all substances. Analysis of 30 pig manure, 20 chicken and turkey dung, and 30 lyophilized soil samples taken in Austria revealed that in pig manure up to 46 mg/kg chlortetracycline, 29 mg/kg oxytetracycline and 23 mg/kg tetracycline could be detected. As representatives of the group of sulfonamides, sulfadimidine in pig manure and sulfadiazine in chicken and turkey dung were detected in significant amounts (maximum concentration, 20 and 91 mg/kg, respectively). Enrofloxacin was particularly observed in chicken and turkey samples. Positive detection of chlortetracycline, enrofloxacin, and ciprofloxacin, in soil samples should be outlined as most important results of this study. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：570 / 579

页数：10

共 36 条

[1] Investigating the environmental transport of human pharmaceuticals to streams in the United Kingdom [J].