Chiroselective re-binding of saccharides to the fibrous aggregates prepared from organic gels of cholesterylphenylboronic acid

被引：29

作者：

Inoue, K ^{[1
]}

Ono, Y ^{[1
]}

Kanekiyo, Y ^{[1
]}

Ishi-I, T ^{[1
]}

Yoshihara, K ^{[1
]}

Shinkai, S ^{[1
]}

机构：

[1] Japan Sci & Technol Corp, CHEMOTRANSFIGURAT Project, Kurume, Fukuoka 839, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 19期

关键词：

D O I：

10.1016/S0040-4039(98)00435-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The xerogel fibers prepared from cholesterylphenylboronic acid or its D- or L-xylose complexes show the chiral discrimination ability in the re-binding of saccharides and partially retain the memory for the original imprinted saccharide. The novel findings indicate that the solgel phase transition in the organic gel is utilizable to the chiral discrimination and even to the molecular imprinting. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2981 / 2984

页数：4

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