Fabrication, functionalization and advanced applications of magnetic hollow materials in confined catalysis and environmental remediation

Magnetic hollow-structured functional hybrid materials with unique architectures and preeminent properties have always been an area of extensive research. They represent a subtle collaboration of hollow architecture, mesoporous nanostructure and magnetic character. Owing to the merits of a large void space, low density, high specific surface area, well-defined active sites and facile magnetic recovery, these materials present promising application projections in numerous fields, such as drug delivery, adsorption, storage, catalysis and many others. In this review, recent progress in the design, synthesis, functionalization and applications of magnetic hollow-meso/nanostructured materials are discussed. The first part of the review has been dedicated to the preparation and functionalization of the materials. The synthetic protocols have been broadly classified into template-assisted and template-free methods and major trends in their synthesis have been elaborated in detail. Furthermore, the benefits and drawbacks of each method are compared. The later part summarizes the application aspects of confined catalysis in organic transformations and environmental remediation such as degradation of organic pollutants, dyes and antibiotics and adsorption of heavy metal ions. Finally, an outlook of future directions in this research field is highlighted.