The selective functionalization of saturated hydrocarbons. Part 46. An investigation of Udenfriend's system under Gif conditions.

被引：2

作者：

Barton, DHR ^{[1
]}

Delanghe, NC ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

TETRAHEDRON | 1998年 / 54卷 / 18期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4020(98)00163-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Under Gif conditions using ascorbic acid as reductant and oxygen as oxidant in pyridine, the selectivity for secondary hydrogen functionalization is exceptional. EDTA (ethylenediamine-tetra-acetic acid) is not needed as a ligand for iron. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：4471 / 4476

页数：6

共 17 条

[1] FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .10. A COMPARATIVE-STUDY OF CHEMICAL AND ELECTROCHEMICAL PROCESSES (GIF AND GIF-ORSAY SYSTEMS) IN PYRIDINE, IN ACETONE AND IN PYRIDINE-CO-SOLVENT MIXTURES
BALAVOINE, G
BARTON, DHR
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[2] The selective functionalization of saturated hydrocarbons. Part 43. Modified Gif oxidation in acetonitrile
Barton, DHR
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[3] Models for non-heme oxidation enzymes
Barton, DHR
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[4] On the mechanism of Gif reactions
Barton, DHR
[J]. CHEMICAL SOCIETY REVIEWS, 1996, 25 (04) : 237 - &
[5] THE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .20. ALKYL HYDROPEROXIDES - REACTION INTERMEDIATES IN THE OXIDATION OF SATURATED-HYDROCARBONS BY GIF-TYPE REACTIONS AND MECHANISTIC STUDIES ON THEIR FORMATION
BARTON, DHR
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (06) : 2147 - 2156
[6] FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .14. FURTHER-STUDIES ON THE MECHANISM OF GIF-TYPE SYSTEMS
BARTON, DHR
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OZBALIK, N
SCHMITT, M
YOUNG, E
BALAVOINE, G
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (18) : 7144 - 7149
[7] Barton DHR, 1997, SYNLETT, P229
[8] The selective functionalization of saturated hydrocarbons .32. Distinction between the Fe-II-Fe-IV and Fe-III-Fe-V manifolds in Gif chemistry. The importance of carboxylic acids for alkane activation. Evidence for a dimeric iron species involved in Gif-type chemistry
Barton, DHR
Hu, B
Taylor, DK
Wahl, RUR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1996, (06): : 1031 - 1041
[9] The selective functionalization of saturated hydrocarbons .10. Aspects of Fe-II based peroxide fragmentation in pyridine solution.
Barton, DHR
Launay, F
[J]. TETRAHEDRON, 1997, 53 (43) : 14565 - 14578
[10] BARTON DHR, UNPUB J CHEM SOC P2

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