Nickel-catalyzed and benzoic acid-promoted direct sulfenylation of unactivated arenes

被引：107

作者：

Yang, Ke ^{[1
]}

Wang, Yuqi ^{[1
]}

Chen, Xinyong ^{[1
]}

Kadi, Adnan A. ^{[2
]}

Fun, Hoong-Kun ^{[2
]}

Sun, Hao ^{[1
]}

Zhang, Yan ^{[1
,2
]}

Lu, Hongjian ^{[1
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, Inst Chem BioMed Sci, Nanjing 210093, Jiangsu, Peoples R China

[2] King Saud Univ, Coll Pharm, Dept Pharmaceut Chem, Riyadh 11451, Saudi Arabia

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 17期

基金：

中国国家自然科学基金;

关键词：

C-H BOND; COUPLING REACTIONS; DIRECT THIOLATION; C(SP(3))-H BONDS; ARYL HALIDES; COPPER; FUNCTIONALIZATION; ACTIVATION; EFFICIENT; ARYLATION;

D O I：

10.1039/c4cc10431e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A nickel-catalyzed and benzoic acid-promoted direct sulfenylation of unactivated arenes using removable 2-(pyridine-2-yl)-isopropylamine as a directing group is described. This strategy provides an efficient access to valuable aryl sulfides with ample substrate scope and a high degree of functional group tolerance.

引用

页码：3582 / 3585

页数：4

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