Cobalt(II) phthalocyanine catalyzed aerobic regeneration of carbonyl compounds from the corresponding oximes in 1-butyl-3-methylimidazolium bromide

被引：30

作者：

Shaabani, Ahmad ^{[1
]}

Farhangi, Elham ^{[1
]}

机构：

[1] Shaheed Beheshti Univ Med Sci, Dept Chem, Tehran, Iran

来源：

APPLIED CATALYSIS A-GENERAL | 2009年 / 371卷 / 1-2期

关键词：

Oximes; Cobalt(II) phthalocyanine; Aerobic oxidation; 1-Butyl-3-methyl imidazolium bromide; IONIC LIQUIDS; MICROWAVE IRRADIATION; SOLVENT-FREE; PYRIDINIUM CHLOROCHROMATE; HETEROGENEOUS OXIDATION; HYDROGEN-PEROXIDE; REFLUX CONDITIONS; DIRECT CONVERSION; MILD CONDITIONS; KETONES;

D O I：

10.1016/j.apcata.2009.09.047

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Metallophthalocyanines (MPcs) catalyzed aerobic regenerations of aldehydes and ketones from aldoximes and ketoximes in various ionic liquids under neutral conditions have been studied. Among the various metallophthalocyanines (MPcs) and ionic liquids (ILs) examined, cobalt(II) phthalocyanine (Co-Pc) exhibited the best performances when used in 1-butyl-3-methylimidazolium bromide ([bmim]Br). Cobalt(II) phthalocyanine and [bmim]Br can be recycled and reused for several runs without any significant loss of catalytic activity. Published by Elsevier B.V.

引用

页码：148 / 152

页数：5

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