Modification of polyethylene's surface properties by high fluence Fe implantation

被引:5
作者
Kisic, Danilo [1 ]
Nenadovic, Milos [1 ]
Barudzija, Tanja [2 ]
Noga, Pavol [3 ]
Vana, Dusan [3 ]
Muska, Martin [3 ]
Rakocevic, Zlatko [1 ]
机构
[1] Univ Belgrade, Vinca Inst Nucl Sci, Lab Atom Phys, Mike Petrovica Alasa 12-14, Belgrade 11351, Serbia
[2] Univ Belgrade, Vinca Inst Nucl Sci, Dept Theoret Phys & Condensed Matter Phys, Mike Petrovica Alasa 12-14, Belgrade 11351, Serbia
[3] Slovak Univ Technol Bratislava, Fac Mat Sci & Technol Trnava, Adv Technol Res Inst, Jana Bottu 25, Trnava 91724, Slovakia
关键词
Ion implantation; Polyethylene; Surface morphology; Sheet resistance; Surface free energy; METAL-ION IMPLANTATION; ELECTRICAL-CONDUCTIVITY; OPTICAL-PROPERTIES; POLYMERS; POLYIMIDE; TEMPERATURE; MORPHOLOGY; SPECTRA; CARBON; PET;
D O I
10.1016/j.nimb.2019.11.022
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
In the presented paper, changes of high-density polyethylene's (HDPE) surface properties along with the changes of chemical composition, as a consequence of Fe ion implantation with different fluences, were investigated. Applied implantation fluences were as follows: 5 x 10(16), 1 x 10(17), 2 x 10(17) and 5 x 10(17) ions cm(-2), while the implantation energy was 95 keV. The samples were analyzed by X-ray photoelectron spectroscopy (XPS), Atomic Force Microscopy (AFM), Four point contact probe, Fourier transform infrared spectroscopy (FTIR) and contact angle measurements. Significant changes in the chemical composition were found by XPS and FTIR, which were followed by changes in surface morphology, increase of roughness, and decrease of sheet resistance that has a percolation threshold that starts for the fluence of 1 x 10(17) ions cm(-2). Surface free energy increases as a consequence of implantation, up to the fluence of 1 x 10(17) ions cm(-2), and then decreases for the 2 higher fluences.
引用
收藏
页码:143 / 153
页数:11
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