Formation and CO2/N2 Switchable Ability of a Novel Copolymer Poly(N,N-Diethylaminoethyl Methacrylate-co-Sodium Vinylsulfonate)

被引：1
作者：
Wang, Jinjing [1 ]
Wang, Huifeng [2 ]
Li, Yan [2 ]
Tian, Li [3 ]
Chen, Shanmin [3 ]
Liu, Qiang [3 ]
Guo, Zhen [3 ]
机构：
[1] Zeng Guofan Sch, Loudi 417707, Peoples R China
[2] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Xiangtan 411201, Peoples R China
[3] Hunan Univ Sci & Technol, Sch Mat Sci & Engn, Hunan Prov Key Lab Controllable Preparat & Funct, Xiangtan 411201, Peoples R China
来源：
POLYMER SCIENCE SERIES A | 2018年 / 60卷 / 05期
关键词：
EMULSIONS;
D O I：
10.1134/S0965545X18050139
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A novel copolymer surfactant has been prepared via a free radical copolymerization of CO2-switchable monomer N,N-diethylaminoethyl methacrylate and the hydrophilic monomer sodium vinyl-sulfonate and characterized. The results of conductivity, dynamic light scattering and cryogenic transmission electron microscopy study showed the change of the microstructure of copolymer in water by adding or removing of CO2. The copolymer aqueous solution was found to exhibit reversible switchability by the bubbling of CO2/N-2.
引用
收藏
页码：612 / 617
页数：6
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共 20 条
  • [1] A guide to the selection of switchable functional groups for CO2-switchable compounds
    Alshamrani, A. K.
    Vanderveen, J. R.
    Jessop, P. G.
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (28) : 19276 - 19288
  • [2] Stimuli-responsive surfactants
    Brown, Paul
    Butts, Craig P.
    Eastoe, Julian
    [J]. SOFT MATTER, 2013, 9 (08) : 2365 - 2374
  • [3] An introduction to the principles and fundamentals of CO2-switchable polymers and polymer colloids
    Cunningham, Michael F.
    Jessop, Philip G.
    [J]. EUROPEAN POLYMER JOURNAL, 2016, 76 : 208 - 215
  • [4] pH-Tunable wormlike micelles based on an ultra-long-chain "pseudo'' gemini surfactant
    Feng, Yujun
    Chu, Zonglin
    [J]. SOFT MATTER, 2015, 11 (23) : 4614 - 4620
  • [5] General Strategy for Making CO2-Switchable Polymers
    Han, Dehui
    Tong, Xia
    Boissiere, Olivier
    Zhao, Yue
    [J]. ACS MACRO LETTERS, 2012, 1 (01) : 57 - 61
  • [6] Green chemistry - Reversible nonpolar-to-polar solvent
    Jessop, PG
    Heldebrant, DJ
    Li, XW
    Eckert, CA
    Liotta, CL
    [J]. NATURE, 2005, 436 (7054) : 1102 - 1102
  • [7] Tertiary amine solvents having switchable hydrophilicity
    Jessop, Philip G.
    Kozycz, Lisa
    Rahami, Zahra Ghoshouni
    Schoenmakers, Dylan
    Boyd, Alaina R.
    Wechsler, Dominik
    Holland, Amy M.
    [J]. GREEN CHEMISTRY, 2011, 13 (03) : 619 - 623
  • [8] A solvent having switchable hydrophilicity
    Jessop, Philip G.
    Phan, Lam
    Carrier, Andrew
    Robinson, Shona
    Duerr, Christoph J.
    Harjani, Jitendra R.
    [J]. GREEN CHEMISTRY, 2010, 12 (05) : 809 - 814
  • [9] pH-Responsive Surface Activity and Solubilization with Novel Pyrrolidone-Based Gemini Surfactants
    Jiang, Zan
    Li, Xuefeng
    Yang, Guangfu
    Cheng, Li
    Cai, Bo
    Yang, Yi
    Dong, Jinfeng
    [J]. LANGMUIR, 2012, 28 (18) : 7174 - 7181
  • [10] Low viscosity alkanolguanidine and alkanolamidine liquids for CO2 capture
    Koech, Phillip K.
    Zhang, Jian
    Kutnyakov, Igor V.
    Cosimbescu, Lelia
    Lee, Suh-Jane
    Bowden, Mark E.
    Smurthwaite, Tricia D.
    Heldebrant, David J.
    [J]. RSC ADVANCES, 2013, 3 (02) : 566 - 572
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