C-C bond formation through oxidatively induced elimination of platinum complexes -: A novel approach towards conjugated macrocycles

被引：123
作者：
Fuhrmann, G
Debaerdemaeker, T
Bäuerle, P
机构：
[1] Univ Ulm, Dept Organ Chem Organ Mat & Combinatorial Chem 2, D-89081 Ulm, Germany
[2] Univ Ulm, Div Xray & Electron Diffract, D-89081 Ulm, Germany
来源：
CHEMICAL COMMUNICATIONS | 2003年 / 08期
关键词：
D O I：
10.1039/b300542a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel and effective method for the synthesis of conjugated macrocycles is described. By the self-assembly of conveniently accessible building blocks to a metalla-macrocycle, and subsequent C-C bond formation through elimination of transition metal units, the strained cyclodimeric terthiophene-diyne 4 -as a precursor for cyclo[8] thiophene 5- was synthesized in a good overall yield.
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收藏
页码：948 / 949
页数：2
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