The adsorption and dissociation of ammonia on small Si clusters surface

被引：14
|
作者：
Qiu, M
Cao, PL [1 ]
Que, DL
机构：
[1] Zhejiang Univ, Dept Phys, Hangzhou 310027, Peoples R China
[2] Zhejiang Univ, State Key Lab High Pur Silicon, Hangzhou 310027, Peoples R China
[3] China Ctr Adv Sci & Technol, World Lab, Beijing 100080, Peoples R China
来源：
SURFACE SCIENCE | 1998年 / 395卷 / 2-3期
基金：
中国国家自然科学基金;
关键词：
ammonia; chemisorption; cluster; dissociation; silicon; theoretical calculation;
D O I：
10.1016/S0039-6028(97)00630-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The nature of the NH3 molecule adsorption and dissociation on small Si clusters surface has been studied using the DV-X alpha method. We also present possible dissociation paths and their energy barriers of the adsorbed NH3 molecule, and confirm the view that NH3 cannot dissociate on the small Si cluster surfaces. (C) 1998 Published by Elsevier Science B.V.
引用
收藏
页码：260 / 267
页数：8
相关论文
共 50 条
  • [1] Adsorption and dissociation of ammonia on small Si clusters surface
    Zhejiang Univ, Hangzhou, China
    Surf Sci, 2-3 (260-267):
  • [2] Adsorption and dissociation of ammonia on small iron clusters
    Zhang, Xilin
    Lu, Zhansheng
    Ma, Dongwei
    Yang, Zongxian
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (01) : 346 - 352
  • [3] The adsorption and dissociation of ammonia on the Si-10 cluster surface
    Qiu, M
    Lee, LQ
    Cao, PL
    Que, DL
    JOURNAL OF PHYSICS-CONDENSED MATTER, 1997, 9 (31) : 6543 - 6553
  • [4] Methane adsorption and dissociation on small Pt clusters
    Xiao, Li
    Wang, Lichang
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [5] Alane adsorption and dissociation on the Si(001) surface
    Smith, R. L.
    Bowler, D. R.
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2017, 29 (39)
  • [6] IR DISSOCIATION OF AMMONIA CLUSTERS
    SNELS, M
    FANTONI, R
    SANDERS, R
    MEERTS, WL
    CHEMICAL PHYSICS, 1987, 115 (01) : 79 - 91
  • [7] Two dissociation pathways of water and ammonia on the Si(001) surface
    Lee, Jung-Yup
    Cho, Jun-Hyung
    JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (37): : 18455 - 18458
  • [8] Thermal desorption of Si clusters from Si and Si-compound surfaces: (I) - spontaneous formation of Si clusters on Si surface and dissociation on Ta surface
    Tanaka, Hideyuki
    Kanayama, Toshihiko
    Shinku/Journal of the Vacuum Society of Japan, 1999, 42 (08): : 749 - 755
  • [9] ADSORPTION AND DISSOCIATION OF AMMONIA ON THE HYDROXYLATED SURFACE OF MAGNESIUM-OXIDE POWDERS
    COLUCCIA, S
    LAVAGNINO, S
    MARCHESE, L
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1987, 83 : 477 - 486
  • [10] Determining the dissociation threshold of ammonia trimers from action spectroscopy of small clusters
    Case, Amanda S.
    Heid, Cornelia G.
    Western, Colin M.
    Crim, F. Fleming
    JOURNAL OF CHEMICAL PHYSICS, 2012, 136 (12):
12345