Molecular and crystal structure of bis{1,4-bis(1,2,4-triazol-1-yl)butane}dibromocadmium(II)

被引：1
作者：
Shen, L. [1 ]
机构：
[1] Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Coll Mat Chem & Chem Engn, Hangzhou 310036, Zhejiang, Peoples R China
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2010年 / 36卷 / 02期
关键词：
COORDINATION POLYMERS; COMPLEX;
D O I：
10.1134/S1070328410020053
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The structure of [Cd(Btb)(2)Br-2] (I) (Btb = 1,4-bis(triazol-1-yl)butane) exhibits a two-dimensional (4,4) network through Btb-bridge in which the Cd(II) atom is in a distorted octahedral environment formed by four nitrogen atoms of the triazoles and two trans-Br atoms. The crystals are monoclinic, space group P2(1)/n with a = 7.6778(6), b = 18.2237(8), c = 8.7655(5) , beta = 113.4534(19)A degrees. The Btb ligand demonstrates the completely anti conformation.
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页码：117 / 119
页数：3
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