Self-Assembly and Chiral Recognition of Quartz Crystal Microbalance Chiral Sensor

被引：14

作者：

Lu, Miao Li ^{[1
]}

Zhang, We Guang ^{[1
]}

Zhang, Sheng ^{[2
]}

Fan, Jun ^{[1
]}

Su, Wen Cui ^{[1
]}

Yin, Xia ^{[1
]}

机构：

[1] S China Normal Univ, Sch Chem & Environm, Guangzhou, Guangdong, Peoples R China

[2] Natl Univ Singapore, Dept Chem, Singapore 117548, Singapore

来源：

CHIRALITY | 2010年 / 22卷 / 04期

基金：

中国国家自然科学基金;

关键词：

QCM; beta-cyclodextrin; aminoethanethiol; UV; chiral discrimination; CYCLODEXTRINS; COADSORPTION; MONOLAYERS; THIOLS; GOLD;

D O I：

10.1002/chir.20756

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

A novel chiral sensor based on the self-assembled monolayer of (6(A)-omega-mercaptoethylureado-6(A)-deoxy)heptakis(2,3-di-0-phenylcarbamoyl)-6(B), 6(C), 6(D), 6(E), 6(F), 6(G)-hexa-0-phenylcarbamoyl-beta-cyclodextrin (Ph-beta-CD-SH) on a quartz crystal transducer for chiral recognition was set up. (R,S)-(+/-)-(3-Methoxyphenyl)ethylamine were recognized by this QCM chiral sensor with a QCM chiral discrimination factor of 1.33. Furthermore, UV spectroscopy was used to investigate the mechanism of host-guest interactions between (6(A)-azido-6(A)-deoxy)heptakis(2,3-di-0-phenylcarbamoyl)-6(B), 6(C), 6(D), 6(E), 6(F), 6(G)-hexa-0-phenylcarbamoyl-beta-cyclodextrin (Ph-beta-CD) and (R,S)-(+/-)-(3-methoxyphenyl) ethylamine. The UV discrimination factor was determined to be 0.066. Chirality 22:411-415, 2010. (C) 2009 Wiley-Liss, Inc.

引用

页码：411 / 415

页数：5

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