Experimental investigation of electrolytic solution for anion exchange membrane water electrolysis

被引：78
作者：
Ito, Hiroshi [1 ]
Kawaguchi, Natsuki [2 ]
Someya, Satoshi [1 ,2 ]
Munakata, Tetsuo [1 ,2 ]
Miyazaki, Naoki [3 ]
Ishida, Masayoshi [3 ]
Nakano, Akihiro [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Res Inst Energy Conservat, 1-2-1 Namiki, Tsukuba, Ibaraki 3058564, Japan
[2] Univ Tokyo, Grad Sch Frontier Sci, Dept Human & Engn Environm Studies, 5-1-5 Kashiwanoha, Kashiwa, Chiba 2778563, Japan
[3] Univ Tsukuba, Dept Engn Mech & Energy, 1-1-1 Tennoudai, Tsukuba, Ibaraki 3058573, Japan
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2018年 / 43卷 / 36期
基金：
日本学术振兴会;
关键词：
Anion exchange membrane; Electrolytic solution; Faraday efficiency; Dew-point; Cross-permeation; HYDROGEN-PRODUCTION; OXYGEN EVOLUTION; CARBON-DIOXIDE; FUEL-CELLS; LOW-COST; PERFORMANCE; ION; CONDUCTIVITY; HYDROXIDE; TRANSPORT;
D O I：
10.1016/j.ijhydene.2018.07.143
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The effect of species and concentration of electrolytic solution on the performance of anion exchange membrane (AEM) water electrolysis is experimentally examined. When potassium hydroxide (KOH) or potassium carbonate (K2CO3) solution is applied for the electrolytic solution, electrolysis is successful under mild alkaline conditions, whereas electrolysis with pure water is quite difficult due to the high resistance of the AEM. AEM electrolysis performance with K2CO3 solution is superior to that with KOH solution, even at similar pH of around 12. Hydrogen content in the anode gas compartment and relative humidity of produced hydrogen are also measured during the electrolysis. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：17030 / 17039
页数：10
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