An effective corrosion inhibitor of N doped carbon dots for Q235 steel in 1 M HCl solution

被引:105
作者
Ye, Yuwei [1 ,2 ]
Zou, Yangjun [1 ]
Jiang, Zilong [1 ]
Yang, Qiumin [1 ]
Chen, Liyong [1 ]
Guo, Shengda [1 ]
Chen, Hao [1 ]
机构
[1] Jiangxi Univ Sci & Technol, Fac Mat Met & Chem, Ganzhou 341000, Peoples R China
[2] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Marine Mat & Related Technol, Zhejiang Key Lab Marine Mat & Protect Technol, Ningbo 315201, Zhejiang, Peoples R China
关键词
Carbon dots; Corrosion; 1 M HCl; Adsorption film; MILD-STEEL; QUANTUM DOTS; GRAPHENE OXIDE; FLUORESCENT N; IONIC LIQUID; CITRIC-ACID; GREEN; DERIVATIVES; ANTICORROSION; EXTRACT;
D O I
10.1016/j.jallcom.2019.152338
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
N doped carbon dots (N-CDs) were prepared by hydrothermal method in methacrylic acid and n-butylamine precursors. The inhibition behavior of N-CDs on Q235 steel in hydrochloric acid environment was discussed via weight loss test, surface characterizations and electrochemistry measurements. Results showed that the as-prepared N-CDs could effectively protect Q235 steel and the inhibition efficiency reached up to 94.96% at 200 mg/L of N-CDs. In the meantime, the impedance modulus was greatly enhanced and the corrosion current density was reduced by one order of magnitude after the addition of N-CDs. Moreover, it could adhere to the steel surface by diffusion and agglomeration effect, resulting in the formation of adsorption film on steel surface. The adsorption mechanism of N-CDs almost complied with the Langmuir adsorption model, containing chemical and physical adsorptions. (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页数:10
相关论文
共 54 条
[1]   Testing validity of the Tafel extrapolation method for monitoring corrosion of cold rolled steel in HCl solutions - Experimental and theoretical studies [J].
Amin, Mohammed A. ;
Khaled, K. F. ;
Fadl-Allah, Sahar A. .
CORROSION SCIENCE, 2010, 52 (01) :140-151
[2]  
[Anonymous], 2015, ANGEW CHEM
[3]   Schiff's base of pyridyl substituted triazoles as new and effective corrosion inhibitors for mild steel in hydrochloric acid solution [J].
Ansari, K. R. ;
Quraishi, M. A. ;
Singh, Ambrish .
CORROSION SCIENCE, 2014, 79 :5-15
[4]   Films formed on copper surface in chloride media in the presence of azoles [J].
Antonijevic, Milan M. ;
Milic, Snezana M. ;
Petrovic, Marija B. .
CORROSION SCIENCE, 2009, 51 (06) :1228-1237
[5]   Electrochemical corrosion behavior of 2A02 Al alloy under an accelerated simulation marine atmospheric environment [J].
Cao, Min ;
Liu, Li ;
Yu, Zhongfen ;
Fan, Lei ;
Li, Ying ;
Wang, Fuhui .
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2019, 35 (04) :651-659
[6]   N, S co-doped carbon dots as effective corrosion inhibitor for carbon steel in CO2-saturated 3.5% NaCl solution [J].
Cen, Hongyu ;
Chen, Zhenyu ;
Guo, Xingpeng .
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2019, 99 :224-238
[7]   Novel nitrogen doped carbon dots for corrosion inhibition of carbon steel in 1 M HCl solution [J].
Cui, Mingjun ;
Ren, Siming ;
Zhao, Haichao ;
Wang, Liping ;
Xue, Qunji .
APPLIED SURFACE SCIENCE, 2018, 443 :145-156
[8]   Carbon dots as new eco-friendly and effective corrosion inhibitor [J].
Cui, Mingjun ;
Ren, Siming ;
Xue, Qunji ;
Zhao, Haichao ;
Wang, Liping .
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 726 :680-692
[9]   One pot solid-state synthesis of highly fluorescent N and S co-doped carbon dots and its use as fluorescent probe for Ag+ detection in aqueous solution [J].
Dinh Khoi Dang ;
Chandrasekaran, Sundaram ;
Yen-Linh Thi Ngo ;
Chung, Jin Suk ;
Kim, Eui Jung ;
Hur, Seung Hyun .
SENSORS AND ACTUATORS B-CHEMICAL, 2018, 255 :3284-3291
[10]   Microstructure and intergranular stress corrosion cracking susceptibility of a SA508-52M-316L dissimilar metal weld joint in primary water [J].
Dong, Lijin ;
Peng, Qunjia ;
Han, En-Hou ;
Ke, Wei ;
Wang, Lei .
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2018, 34 (08) :1281-1292