Synthesis, crystal structure and biological activity of the nickel(II) complex of 2,6-diacetylpyridinedihydrazone

被引：10

作者：

Azaz, A. Dilek ^{[1
]}

Celen, Selma

Namli, Hilmi

Turhan, Onur

Kurtaran, Raif

Kazak, Canan

Arslan, N. Burcu

机构：

[1] Balikesir Univ Art & Sci Fac, Dept Biol & Chem, TR-10145 Balikesir, Turkey

[2] Ondokuz Mayis Univ, Fac Arts Sci, Dept Phys, TR-55139 Kurupelit, Turkey

来源：

TRANSITION METAL CHEMISTRY | 2007年 / 32卷 / 07期

关键词：

Bioactivity - Crystal structure - Ligands - Metal complexes - Nickel - Synthesis (chemical);

D O I：

10.1007/s11243-007-0242-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A complex of Ni-II with 2,6-diacetylpyridinedihydrazone (L) towards nickel(II) has been prepared and characterized by means of elemental analyses, IR, electronic spectra and single crystal X-ray analyses. [NiL2](NO3) was crystallized in the tetragonal space group P-4 21 c. The complex exhibits the expected coordination sphere with six nitrogen atoms coordinated to the central Ni-II with a deformation from pseudo-octahedral geometry. Antimicrobial activities of the ligand and its complex were investigated.

引用

页码：884 / 888

页数：5

共 19 条

[1]

[Anonymous], 1997, SHELX97 PROGRAMS CRY

[2]

Azaz Ayse Dilek, 2003, Turkish Journal of Biology, V27, P117

[3] METAL COMPLEXES DERIVED FROM SUBSTITUTED HYDRAZONES OF 2,6-DIACETYLPYRIDINE [J].

CURRY, JD ;

ROBINSON, MA ;

BUSCH, DH .

INORGANIC CHEMISTRY, 1967, 6 (08) :1570-&

[4]

Farrugia L.J., 1997, J APPL CRYSTALLOGR, V30, P565

[5]

Hadacek F, 2000, PHYTOCHEM ANALYSIS, V11, P137, DOI 10.1002/(SICI)1099-1565(200005/06)11:3&lt

[6]

137::AID-PCA514&gt

[7]

3.0.CO

[8]

2-I

[9] Synthesis, characterization and antimicrobial activity of cobalt(II), nickel(II)and copper(II) complexes with new asymmetrical Schiff base ligands derived from 7-formyanil-substituted diamine-sulphoxine and acetylacetone [J].

Hanna, WG ;

Moawad, MM .

TRANSITION METAL CHEMISTRY, 2001, 26 (06) :644-651

[10]

Hasenekoglu I., 1990, LAB TECHNIQUES MICRO, P66

← 1 2 →