Classical-Fenton and Photo-Fenton oxidation of wastewater arising from cosmetic automobile care products

被引:7
作者
Cuce, Huseyin [1 ]
Aydin Temel, Fulya [2 ]
机构
[1] Giresun Univ, Fac Engn, Dept Geomat Engn, Giresun, Turkey
[2] Giresun Univ, Dept Environm Engn, Fac Engn, Giresun, Turkey
关键词
Classical-Fenton; cosmetic wastewater; kinetic; Photo-Fenton; removal; BOX-BEHNKEN DESIGN; WASTEWATERS; DECOLORIZATION; COAGULATION; MODEL;
D O I
10.1002/ep.13701
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The goal of the study is to investigate Classical-Fenton and Photo-Fenton oxidation from Fenton-based advanced oxidation processes for wastewater treatment arising from cosmetic automobile care products. The main factors that affected Fenton processes (pH, H2O2 doses, Fe2+ doses, and H2O2/Fe2+ ratios) were examined to optimize the operating conditions in batch reactors. The optimal pH values for both systems were found as 3. The optimum experimental conditions were determined as 300 mg/L of Fe2+ dosage, 1050 mg/L of H2O2 dosage and 600/300 of H2O2/Fe2+ ratios for Classical-Fenton; 300 mg/L of Fe2+ dosage, 900 mg/L of H2O2 dosage, and 600/300 of H2O2/Fe2+ rates for Photo-Fenton process. In all these cases, COD removals were obtained as 75% in Classical-Fenton process and around 85% in Photo-Fenton process. The kinetic model results indicated that the experimental data was represented well by Behnajady-Modirshahla-Ghanbery model (R-2 = 0.99) for both Fenton processes. Finally, it is concluded that Classical-Fenton and Photo-Fenton processes were effective for COD removal from cosmetic wastewater. Photo-Fenton process as an oxidative removal process was exhibited more promising results due to rapid degradation, higher removal performance, fewer reagents usage, simple handling, and protecting of process effectiveness.
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页数:10
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