A L-tryptophan sensor based on tellurium nanorods modified glassy carbon electrode

被引:2
作者
Sheng, Qinglin [1 ]
Liu, Ruixiao [1 ]
Zhang, Hongfang [1 ]
Zheng, Jianbin [1 ]
机构
[1] NW Univ Xian, Shaanxi Prov Key Lab Electroanalyt Chem, Inst Analyt Sci, Xian 710069, Shaanxi, Peoples R China
关键词
Tellurium nanorods; L-tryptophan; Amperometry; Electrochemical sensor; NONENZYMATIC ELECTROCHEMICAL SENSOR; PASTE ELECTRODE; CAPILLARY-ELECTROPHORESIS; SENSITIVE DETERMINATION; FLUORESCENCE DETECTION; URIC-ACID; NANOPARTICLES; GLUCOSE; NANOTUBES; NANOWIRES;
D O I
10.1007/s13738-016-0833-y
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An electrochemical l-tryptophan sensor based on tellurium nanorods modified glassy carbon electrode was proposed. The tellurium nanorods were synthesized by a chemical reduction method. The morphology and structures of the nanorods were characterized by scanning electron microscope (SEM) and transmission electron microscope (TEM). Owing to the special structure of the tellurium nanorods, the sensor exhibits excellent electrocatalytic ability towards the oxidation of l-tryptophan and shows linearity in the range from 0.02 to 11.48 mu M with a sensitivity of 256 mu A mM(-1) cm(-2) with a correlation coefficient of 0.9945. The detection limit was 0.01 mu M with signal-to-noise ratio of 3, and the response time was found to be 2 s. Moreover, the sensor also exhibited long-term stability, good reproducibility and anti-interference, thus holding promise for sensing of l-tryptophan in practice.
引用
收藏
页码:1189 / 1195
页数:7
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