An electrochemical l-tryptophan sensor based on tellurium nanorods modified glassy carbon electrode was proposed. The tellurium nanorods were synthesized by a chemical reduction method. The morphology and structures of the nanorods were characterized by scanning electron microscope (SEM) and transmission electron microscope (TEM). Owing to the special structure of the tellurium nanorods, the sensor exhibits excellent electrocatalytic ability towards the oxidation of l-tryptophan and shows linearity in the range from 0.02 to 11.48 mu M with a sensitivity of 256 mu A mM(-1) cm(-2) with a correlation coefficient of 0.9945. The detection limit was 0.01 mu M with signal-to-noise ratio of 3, and the response time was found to be 2 s. Moreover, the sensor also exhibited long-term stability, good reproducibility and anti-interference, thus holding promise for sensing of l-tryptophan in practice.
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Univ Pretoria, Dept Chem, ZA-0002 Pretoria, South AfricaCSIR, Energy & Proc Unit, ZA-0001 Pretoria, South Africa
Adekunle, Abolanle S.
Agboola, Bolade O.
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CSIR, Energy & Proc Unit, ZA-0001 Pretoria, South AfricaCSIR, Energy & Proc Unit, ZA-0001 Pretoria, South Africa
Agboola, Bolade O.
Pillay, Jeseelan
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MINTEK, Adv Mat Div, ZA-2125 Randburg, South AfricaCSIR, Energy & Proc Unit, ZA-0001 Pretoria, South Africa
Pillay, Jeseelan
Ozoemena, Kenneth I.
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机构:
CSIR, Energy & Proc Unit, ZA-0001 Pretoria, South Africa
Univ Pretoria, Dept Chem, ZA-0002 Pretoria, South AfricaCSIR, Energy & Proc Unit, ZA-0001 Pretoria, South Africa
机构:
Univ Pretoria, Dept Chem, ZA-0002 Pretoria, South AfricaCSIR, Energy & Proc Unit, ZA-0001 Pretoria, South Africa
Adekunle, Abolanle S.
Agboola, Bolade O.
论文数: 0引用数: 0
h-index: 0
机构:
CSIR, Energy & Proc Unit, ZA-0001 Pretoria, South AfricaCSIR, Energy & Proc Unit, ZA-0001 Pretoria, South Africa
Agboola, Bolade O.
Pillay, Jeseelan
论文数: 0引用数: 0
h-index: 0
机构:
MINTEK, Adv Mat Div, ZA-2125 Randburg, South AfricaCSIR, Energy & Proc Unit, ZA-0001 Pretoria, South Africa
Pillay, Jeseelan
Ozoemena, Kenneth I.
论文数: 0引用数: 0
h-index: 0
机构:
CSIR, Energy & Proc Unit, ZA-0001 Pretoria, South Africa
Univ Pretoria, Dept Chem, ZA-0002 Pretoria, South AfricaCSIR, Energy & Proc Unit, ZA-0001 Pretoria, South Africa