Phosphonic acid-modiried barium titanate polymer nanocomposites with high permittivity and dielectric strength

被引:535
作者
Kim, Philseok
Jones, Simon C.
Hotchkiss, Peter J.
Haddock, Joshua N.
Kippelen, Bernard
Marder, Seth R.
Perry, Joseph W.
机构
[1] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA
[2] Georgia Inst Technol, Ctr Organ Photon & Elect, Atlanta, GA 30332 USA
[3] Georgia Inst Technol, Sch Elect & Comp Engn, Atlanta, GA 30332 USA
关键词
CONSTANT; COMPOSITES; CAPACITOR;
D O I
10.1002/adma.200602422
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Phosphonic acids act as robust surface modifiers on barium titanate (BT) nanoparticles (NPs) (see figure), affording homogeneous, high-volume-fraction composites of such NPs in polymeric hosts by simple solution processing. Pentafluorobenzyl phosphonic acid-modified BT nanocomposite films in poly(vinylidenefluoride-co-hexafluoropropylene) show large relative permittivities and unusually high dielectric breakdown strengths.
引用
收藏
页码:1001 / +
页数:6
相关论文
共 25 条
[1]   High-dielectric-constant ceramic-powder polymer composites [J].
Bai, Y ;
Cheng, ZY ;
Bharti, V ;
Xu, HS ;
Zhang, QM .
APPLIED PHYSICS LETTERS, 2000, 76 (25) :3804-3806
[2]   Finite difference simulations of permittivity and electric field statistics in ceramic-polymer composites for capacitor applications [J].
Calame, J. P. .
JOURNAL OF APPLIED PHYSICS, 2006, 99 (08)
[3]   Relationships between suspension formulations and the properties of BaTiO3/epoxy composite films for integral capacitors [J].
Cho, SD ;
Paik, KW .
51ST ELECTRONIC COMPONENTS & TECHNOLOGY CONFERENCE, 2001, :1418-1422
[4]   Novel ferroelectric polymer composites with high dielectric constants [J].
Dang, ZM ;
Lin, YH ;
Nan, CW .
ADVANCED MATERIALS, 2003, 15 (19) :1625-+
[5]   Dielectric behavior of three-phase percolative Ni-BaTiO3/polyvinylidene fluoride composites [J].
Dang, ZM ;
Shen, Y ;
Nan, CW .
APPLIED PHYSICS LETTERS, 2002, 81 (25) :4814-4816
[6]   Self-assembled monolayers of alkylphosphonic acids on metal oxides [J].
Gao, W ;
Dickinson, L ;
Grozinger, C ;
Morin, FG ;
Reven, L .
LANGMUIR, 1996, 12 (26) :6429-6435
[7]  
Gilbert L.J., 2006, CERAMIC T ADV ELECT, V179, P17
[8]   Copper compatible barium titanate thin films for embedded passives [J].
Ihlefeld, J ;
Laughlin, B ;
Hunt-Lowery, A ;
Borland, W ;
Kingon, A ;
Maria, JP .
JOURNAL OF ELECTROCERAMICS, 2005, 14 (02) :95-102
[9]   DIELECTRIC-CONSTANT FOR BINARY PIEZOELECTRIC 0-3 COMPOSITES [J].
JAYASUNDERE, N ;
SMITH, BV .
JOURNAL OF APPLIED PHYSICS, 1993, 73 (05) :2462-2466
[10]   Phenylphosphonic acid functionalization of indium tin oxide: Surface chemistry and work functions [J].
Koh, Sharon E. ;
McDonald, Krystal D. ;
Holt, David H. ;
Dulcey, Charles S. ;
Chaney, John A. ;
Pehrsson, Pehr E. .
LANGMUIR, 2006, 22 (14) :6249-6255