Propanal Hydroamination with p-Aminobenzoic Acid

被引：2

作者：

Magdalinova, N. A. ^{[1
]}

Volkova, T. G. ^{[1
]}

Klyuev, M. V. ^{[1
]}

Gruzdev, M. S. ^{[2
]}

机构：

[1] Ivanovo State Univ, Ivanovo, Russia

[2] Russian Acad Sci, Inst Solut Chem, Ivanovo 153045, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 46卷 / 05期

关键词：

Benzoic Acid; Enamine; Tautomeric Equilibrium; Separate Precipitate; Apparent Reaction Rate;

D O I：

10.1134/S1070428010050052

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The propanal hydroamination was studied. It was found that the reaction in ethanol proceeded faster than in 2-propanol. By (1)H and (13)C NMR method the existence was proved of a tautomeric equilibrium in ethanol solution between 4-(propylideneamino)benzoic acid and its enamine form, 4-(prop-1-en-1-ylamino)benzoic acid.

引用

页码：634 / 636

页数：3