Synthesis and characterisation of polymer supported Schiff base metal chelates

被引：0
|
作者：
Chettiyar, KS [1 ]
Sreekumar, K [1 ]
机构：
[1] Cochin Univ Sci & Technol, Dept Appl Chem, Kochi 682022, Kerala, India
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2003年 / 42卷 / 03期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Divinyl benzene (DVB)-crosslinked polystyrene has been functionalised to introduce thiosemicarbazone ligand function. This Schiff base thiosemicarbazone ligand is used to prepare chelates of Fe(III), Co(II), Ni(II), Cu(II) and Zn(II). The factors influencing metal complexation like temperature, pH, influence of solvent etc are examined. The polymeric metal complexes are well characterised by spectral techniques and assigned a proper geometry on the basis of analytical. magnetic measurement and spectral data.
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页码：499 / 505
页数：7
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