All-solid-state reflectance-type electrochromic devices using iridium tin oxide film as counter electrode

被引:35
作者
Niwa, Tatsuo [1 ]
Takai, Osamu [1 ]
机构
[1] Nagoya Univ, Grad Sch Engn, Dept Mat Phys & Energy Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
关键词
Electrochromic device; Tungsten oxide; Thin film; Iridium oxide; Solid electrolyte; Tantalum oxide; Tin oxide; TANTALUM OXIDE;
D O I
10.1016/j.tsf.2010.04.030
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We prepared an all-solid-state reflectance-type electrochromic device (ECD), consisting of the following five layers: Al/WO3/Ta2O5/IrxSn1-xO2/ITO. Using RF ion plating, we prepared a film containing dispersed iridium oxide in a tin oxide matrix; this film acts as the counter electrode in the all-solid-state ECD. Protons were used as coloration ions in the ECD. The size of the ECD was 150 cm(2), and the reflectance changed between more than 60% from 15%. The coloration and bleaching response times were less than a few seconds. We analyze the optical characteristics of the ECD, and report the results of a consecutive drive test and a high-temperature heat resistance test. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:5340 / 5344
页数:5
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