The energetic 3-trinitromethyl-5-nitramino-1H-1,2,4-triazole and nitrogen-rich salts

被引：22
|
作者：
Hermann, Tobias S. [1 ]
Klapoetke, Thomas M. [1 ]
Krumm, Burkhard [1 ]
Stierstorfer, Joerg [1 ]
机构：
[1] Ludwig Maximilian Univ Munich, Dept Chem, Butenandtstr 5-13 D, D-81377 Munich, Germany
来源：
NEW JOURNAL OF CHEMISTRY | 2017年 / 41卷 / 08期
关键词：
POLYNITRO; ACID;
D O I：
10.1039/c7nj00695k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of 3-trinitromethyl-5-nitramino-1H-1,2,4-triazole (1) is described. This triazole is a powerful energetic compound due to its high nitrogen-and oxygen-content. Selected nitrogen-rich salts were also prepared in order to tune the performance and sensitivity values. The compounds are characterised by vibrational and NMR spectroscopy, and elemental analysis. The structure of 1 was determined by X-ray diffraction. The sensitivities were measured according to BAM standards and energetic performances calculated by EXPLO5 6.03.
引用
收藏
页码：3068 / 3072
页数：5
相关论文
共 50 条
  • [21] Theoretical study of the stabilities and detonation performance of 5-nitro-3-trinitromethyl-1H-1,2,4-triazole and its derivatives
    Xueli Zhang
    Xuedong Gong
    Journal of Molecular Modeling, 2015, 21
  • [22] Nitrogen-Rich Salts Based on Energetic Nitroaminodiazido[1,3,5]triazine and Guanazine
    Huang, Yangen
    Zhang, Yanqiang
    Shreeve, Jean'ne M.
    CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (05) : 1538 - 1546
  • [23] Energetic polymer salts from 1-vinyl-1,2,4-triazole derivatives
    Xue, Hong
    Gao, Haixiang
    Shreeve, Jean'ne M.
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (07) : 2414 - 2421
  • [24] Nitrogen-Rich Energetic Salts of Bis-Heterocycle-Substituted 1,2,3-Triazole (HTANFT)
    Bian, Chengming
    Wang, Kai
    Liang, Lixuan
    Zhang, Man
    Li, Chuan
    Zhou, Zhiming
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, (35) : 6022 - 6030
  • [25] Simple, nitrogen-rich, energetic salts of 5-nitrotetrazole
    Klapoetke, Thomas M.
    Mayer, Peter
    Sabate, Caries Miro
    Welch, Jan M.
    Wiegand, Nikolai
    INORGANIC CHEMISTRY, 2008, 47 (13) : 6014 - 6027
  • [26] Novel family of nitrogen-rich energetic (1,2,4-triazolyl) furoxan salts with balanced performance
    Larin, Alexander A.
    Pivkina, Alla N.
    Ananyev, Ivan V.
    Khakimov, Dmitry V.
    Fershtat, Leonid L.
    FRONTIERS IN CHEMISTRY, 2022, 10
  • [27] Nitrogen-Rich Energetic Monoanionic Salts of 3,4-Bis(1H-5-tetrazolyl)furoxan
    Huang, Haifeng
    Zhou, Zhiming
    Liang, Lixuan
    Song, Jinhong
    Wang, Kai
    Cao, Dan
    Sun, Wenwen
    Bian, Chengming
    Xue, Min
    CHEMISTRY-AN ASIAN JOURNAL, 2012, 7 (04) : 707 - 714
  • [28] 5-amino-3-trifluoromethyl-1H-1,2,4-triazole
    Borbulevych, OY
    Shishkin, OV
    Desenko, SM
    Chernenko, VN
    Orlov, VD
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1998, 54 : 442 - 444
  • [29] Energetic Nitrogen-Rich Salts of 1-(2-Hydroxyethyl)-5-nitriminotetrazole
    Fischer, Niko
    Klapoetke, Thomas M.
    Stierstorfer, Joerg
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2011, (28) : 4471 - 4480
  • [30] Nitramino- and Dinitromethyl-Substituted 1,2,4-Triazole Derivatives as High-Performance Energetic Materials
    Tang, Yongxing
    Dharavath, Srinivas
    Imler, Gregory H.
    Parrish, Damon A.
    Shreeve, Jean'ne M.
    CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (38) : 9185 - 9191
12345