The energetic 3-trinitromethyl-5-nitramino-1H-1,2,4-triazole and nitrogen-rich salts

被引：22
|
作者：
Hermann, Tobias S. [1 ]
Klapoetke, Thomas M. [1 ]
Krumm, Burkhard [1 ]
Stierstorfer, Joerg [1 ]
机构：
[1] Ludwig Maximilian Univ Munich, Dept Chem, Butenandtstr 5-13 D, D-81377 Munich, Germany
来源：
NEW JOURNAL OF CHEMISTRY | 2017年 / 41卷 / 08期
关键词：
POLYNITRO; ACID;
D O I：
10.1039/c7nj00695k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of 3-trinitromethyl-5-nitramino-1H-1,2,4-triazole (1) is described. This triazole is a powerful energetic compound due to its high nitrogen-and oxygen-content. Selected nitrogen-rich salts were also prepared in order to tune the performance and sensitivity values. The compounds are characterised by vibrational and NMR spectroscopy, and elemental analysis. The structure of 1 was determined by X-ray diffraction. The sensitivities were measured according to BAM standards and energetic performances calculated by EXPLO5 6.03.
引用
收藏
页码：3068 / 3072
页数：5
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