A new diphosphine-carbonyl complex of ruthenium: an efficient precursor for C-C and C-N bond coupling catalysis

被引：15

作者：

Mukherjee, Aparajita ^{[1
]}

Hrovat, David A. ^{[2
,3
]}

Richmond, Michael G. ^{[3
]}

Bhattacharya, Samaresh ^{[1
]}

机构：

[1] Jadavpur Univ, Inorgan Chem Sect, Dept Chem, Kolkata 700032, India

[2] Univ North Texas, Ctr Adv Sci Comp & Modeling, Denton, TX 76203 USA

[3] Univ North Texas, Dept Chem, Denton, TX 76203 USA

来源：

DALTON TRANSACTIONS | 2018年 / 47卷 / 30期

基金：

美国国家科学基金会;

关键词：

SET MODEL CHEMISTRY; X-RAY-STRUCTURE; WATER OXIDATION; TOTAL ENERGIES; HYDROGENATION; ACTIVATION; PALLADIUM; LIGANDS; ALKYNES; COORDINATION;

D O I：

10.1039/c8dt01085d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of 1,2-bis(diphenylphosphino) benzene (dppbz) with [{Ru(CO)(2)Cl-2}(n)] affords [Ru(dppbz)(CO)(2)Cl-2], where the two carbonyls are mutually cis and the two chlorides are trans. The molecular structure of [Ru(dppbz)(CO)(2)Cl-2], has been determined by X-ray crystallography, and the stability of the different available stereoisomers has been computationally evaluated. [Ru(dppbz)(CO)(2)Cl-2] has been found to serve as an excellent pre-catalyst for catalytic Suzuki-type C-C coupling and Buchwald-type C-N coupling reactions.

引用

页码：10264 / 10272

页数：9

共 83 条

[1] Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C-H/Het-H Bond Functionalizations [J].

Ackermann, Lutz .

ACCOUNTS OF CHEMICAL RESEARCH, 2014, 47 (02) :281-295

[2] Ruthenium-Catalyzed Oxidative Synthesis of 2-Pyridones through C-H/N-H Bond Functionalizations [J].

Ackermann, Lutz ;

Lygin, Alexander V. ;

Hofmann, Nora .

ORGANIC LETTERS, 2011, 13 (12) :3278-3281

[3] Carboxylate-Assisted Transition-Metal-Catalyzed C-H Bond Functionalizations: Mechanism and Scope [J].

Ackermann, Lutz .

CHEMICAL REVIEWS, 2011, 111 (03) :1315-1345

[4] DESIGNED SYNTHESIS OF MONONUCLEAR TRIS(HETEROLEPTIC) RUTHENIUM COMPLEXES CONTAINING BIDENTATE POLYPYRIDYL LIGANDS [J].

ANDERSON, PA ;

DEACON, GB ;

HAARMANN, KH ;

KEENE, FR ;

MEYER, TJ ;

REITSMA, DA ;

SKELTON, BW ;

STROUSE, GF ;

THOMAS, NC ;

TREADWAY, JA ;

WHITE, AH .

INORGANIC CHEMISTRY, 1995, 34 (24) :6145-6157

[5] ENERGY-ADJUSTED ABINITIO PSEUDOPOTENTIALS FOR THE 2ND AND 3RD ROW TRANSITION-ELEMENTS [J].

ANDRAE, D ;

HAUSSERMANN, U ;

DOLG, M ;

STOLL, H ;

PREUSS, H .

THEORETICA CHIMICA ACTA, 1990, 77 (02) :123-141

[6]

[Anonymous], CHEM REV

[7]

Arockiam PB, 2012, CHEM REV, V112, P5879, DOI [10.1021/cr300153J, 10.1021/cr300153j]

[8] Insights into amine binding to biaryl phosphine palladium oxidative addition complexes and reductive elimination from biaryl phosphine arylpalladium amido complexes via density functional theory [J].

Barder, Timothy E. ;

Buchwald, Stephen L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (39) :12003-12010

[9] DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE [J].

BECKE, AD .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5648-5652

[10] MacMolPlt: A graphical user interface for GAMESS [J].

Bode, BM ;

Gordon, MS .

JOURNAL OF MOLECULAR GRAPHICS & MODELLING, 1998, 16 (03) :133-+

← 1 2 3 4 5 6 7 8 9 →