A new class of non-corrosive, highly efficient electrolytes for rechargeable magnesium batteries

被引：368

作者：

Zhao-Karger, Zhirong ^{[1
]}

Bardaji, Maria Elisa Gil ^{[2
]}

Fuhr, Olaf ^{[2
,3
]}

Fichtner, Maximilian ^{[1
,2
]}

机构：

[1] HIU, Albert Einstein Allee 11, D-89081 Ulm, Germany

[2] Karlsruhe Inst Technol, Inst Nanotechnol, POB 3640, D-76021 Karlsruhe, Germany

[3] KIT, KNMF, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2017年 / 5卷 / 22期

关键词：

ELECTROCHEMISTRY; PERFORMANCE; STABILITY; SYSTEMS; ANIONS; SALTS;

D O I：

10.1039/c7ta02237a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Fluorinated alkoxyborate based magnesium electrolytes exhibit a high anodic stability, high ionic conductivity and high coulombic efficiency of magnesium deposition. Owing to the non-corrosive, chemically stable nature and the robust, economic synthesis, this design concept of ion conducting salts opens a promising avenue towards the realization of high-energy magnesium batteries.

引用

页码：10815 / 10820

页数：6

共 39 条

[1] Prototype systems for rechargeable magnesium batteries [J].

Aurbach, D ;

Lu, Z ;

Schechter, A ;

Gofer, Y ;

Gizbar, H ;

Turgeman, R ;

Cohen, Y ;

Moshkovich, M ;

Levi, E .

NATURE, 2000, 407 (6805) :724-727

[2]

Aurbach D, 1999, NONAQUEOUS ELECTROCHEMISTRY, P137

[3] Na[B(hfip)4] (hfip = OC(H)(CF3)2): a weakly coordinating anion salt and its first application to prepare ionic liquids [J].

Bulut, Safak ;

Klose, Petra ;

Krossing, Ingo .

DALTON TRANSACTIONS, 2011, 40 (32) :8114-8124

[4] Synthesis and properties of magnesium tetrahydroborate, Mg(BH4)2 [J].

Chlopek, Krzysztof ;

Frommen, Christoph ;

Leon, Aline ;

Zabara, Oleg ;

Fichtner, Maximilian .

JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (33) :3496-3503

[5] Novel, electrolyte solutions comprising fully inorganic salts with high anodic stability for rechargeable magnesium batteries [J].

Doe, Robert E. ;

Han, Ruoban ;

Hwang, Jaehee ;

Gmitter, Andrew J. ;

Shterenberg, Ivgeni ;

Yoo, Hyun Deog ;

Pour, Nir ;

Aurbach, Doron .

CHEMICAL COMMUNICATIONS, 2014, 50 (02) :243-245

[6] Review-Development of Advanced Rechargeable Batteries: A Continuous Challenge in the Choice of Suitable Electrolyte Solutions [J].

Erickson, Evan M. ;

Markevich, Elena ;

Salitra, Gregory ;

Sharon, Daniel ;

Hirshberg, Daniel ;

de la Llave, Ezequiel ;

Shterenberg, Ivgeni ;

Rozenman, Ariel ;

Frimer, Aryeh ;

Aurbach, Doron .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2015, 162 (14) :A2424-A2438

[7]

Garsuch A., 2013, WO, Patent No. [2015/ 007586, 2015007586]

[8] Organometallic Electrochemistry Based on Electrolytes Containing Weakly-Coordinating Fluoroarylborate Anions [J].

Geiger, William E. ;

Barriere, Frederic .

ACCOUNTS OF CHEMICAL RESEARCH, 2010, 43 (07) :1030-1039

[9] NONAQUEOUS ELECTROCHEMISTRY OF MAGNESIUM - APPLICATIONS TO ENERGY-STORAGE [J].

GREGORY, TD ;

HOFFMAN, RJ ;

WINTERTON, RC .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (03) :775-780

[10] Boron-based electrolyte solutions with wide electrochemical windows for rechargeable magnesium batteries [J].

Guo, Yong-sheng ;

Zhang, Fan ;

Yang, Jun ;

Wang, Fei-fei ;

NuLi, Yanna ;

Hirano, Shin-ichi .

ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (10) :9100-9106

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