Synthesis of 4-aminothiophenol functionalized quantum dots to sensitize silver nanowires and its application for solar cells

被引:6
作者
Kong, Peng [1 ]
Wang, Rui [1 ]
Zhang, Chen [1 ]
Du, Zhongjie [1 ]
Li, Hangquan [1 ]
Zou, Wei [1 ]
机构
[1] Beijing Univ Chem Technol, Minist Educ, Key Lab Carbon Fiber & Funct Polymers, Beijing 100029, PR, Peoples R China
基金
中国国家自然科学基金;
关键词
Quantum dots; Functional; Silver nanowires; Nanocomposites; Energy conversion; PHOTOANODE; EFFICIENCY; FILMS;
D O I
10.1016/j.synthmet.2017.02.004
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A novel strategy for synthesizing a quantum dot (QD)-sensitized silver nanowire (AgNW) nanocomposite has been reported. 4-aminothiophenol (PATP) functionalized quantum dots (QDs-PATP) were prepared using the thiol ( -SH) end of PATP molecules strongly bound to the surface of QDs via a ligand exchange technique. AgNWs could bind to the remaining amino group ( -NH2) of PATP via self-assembly techniques, and quantum dot-sensitized silver nanowires were then formed. The nanocomposite is denoted as QDs-PATP@AgNWs. The photovoltaic properties of a quantum dot -sensitized solar cell (QDSSC) based on QDs-PATP@AgNWs were investigated. Under AM 1.5 illumination, the QDSSC reached a peak conversion efficiency of 3.34%. This finding suggests that QDs-PATP@AgNWs had potential applications as a photoanode for QDSSC. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:50 / 55
页数:6
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