Homologous series of iron pnictide oxide superconductors (Fe2As2)x[Can+1(Sc,Ti)nOy] (n=3,4,5) with extremely thick blocking layers

被引:68
作者
Ogino, Hiraku [1 ,2 ]
Sato, Shinya [1 ,2 ]
Kishio, Kohji [1 ,2 ]
Shimoyama, Jun-ichi [1 ,2 ]
Tohei, Tetsuya [3 ]
Ikuhara, Yuichi [3 ]
机构
[1] Univ Tokyo, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
[2] JST TRIP, Chiyoda Ku, Sanban, Tokyo 1020075, Japan
[3] Univ Tokyo, Inst Engn Innovat, Bunkyo Ku, Tokyo 1138656, Japan
关键词
calcium compounds; crystal structure; high-temperature superconductors; iron compounds; multilayers; superconducting transition temperature;
D O I
10.1063/1.3478850
中图分类号
O59 [应用物理学];
学科分类号
摘要
We have discovered homologous series of iron pnictide superconductors (Fe2As2)[Can+1(Sc,Ti)(n)O-y] (n=3,4,5). These compounds have extremely thick blocking layers up to quintuple perovskite layers sandwiched by the Fe2As2 layers. These samples exhibited bulk superconductivity with relatively high T-c up to 42 K. The relationship between T-c and the iron-plane interlayer distance suggested that T-c of the iron based superconductor is basically determined by the local structure of Fe2As2 layer. (C) 2010 American Institute of Physics. [doi:10.1063/1.3478850]
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页数:3
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