Analysis of structural modifications in γ-irradiated PbO-B2O3-SiO2 glasses by FTIR spectroscopy

被引:45
作者
Baccaro, S.
Monika
Sharma, G.
Thind, K. S.
Singh, Devinder
Cecillia, A.
机构
[1] ENEA, FIM, I-00060 Rome, Italy
[2] Guru Nanak Dev Univ, Dept Phys, Amritsar 143005, Punjab, India
关键词
borosilicate glasses; gamma-irradiation; IR spectra; NBOs;
D O I
10.1016/j.nimb.2007.04.214
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
The effect of gamma-irradiation on the structure of lead borosilicate glasses of varying composition has been probed by FTIR spectroscopy, before and immediately after gamma-irradiation. The glasses were irradiated at Calliope Co-60 plant (RC ENEA Casaccia, Rome), and the spectra were recorded after absorbed doses of 50 Gy, 500 Gy, and 4 kGy. The structural analysis have been made considering both the effect of composition and of irradiation. The experimental results clearly indicate that after irradiation a significant change in structure of borosilicate glass network is observed. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:613 / 618
页数:6
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