Nanoparticulate AlO(OH)n filled polyvinylidenefluoride-co-hexafluoropropylene based microporous membranes for lithium ion batteries

被引:14
作者
Aravindan, Vanchiappan [1 ]
Vickraman, Palanisamy [1 ]
机构
[1] Gandhigram Rural Univ, Dept Phys, Gandhigram 624302, India
关键词
POLYMER ELECTROLYTES; COMPOSITE ELECTROLYTES; TRANSPORT-PROPERTIES; TOUGHNESS; STORAGE;
D O I
10.1063/1.3122671
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This paper presents the nanosized AlO(OH)(n) incorporated microporous membranes by phase inversion technique, for the first time, using polyvinylidenefluoride-co-hexafluoropropylene as a host matrix. The transport properties of the membranes were studied and analyzed by various techniques, namely, alternating current impedance spectroscopy, Fourier transform infrared spectroscopy, Raman spectra, differential scanning calorimetry, tensile strength, X-ray diffraction, and scanning electron microscope. Further, Brunauer-Emmett-Teller surface area measurements, percentage of crystallinity, electrolyte uptake, porosity, activation energy, and Mac-Mullin number were also calculated for these microporous membranes. (C) 2009 American Institute of Physics. [DOI: 10.1063/1.3122671]
引用
收藏
页数:11
相关论文
共 22 条
[1]   Polyvinylidenefluoride-hexafluoropropylene based nanocomposite polymer electrolytes (NCPE) complexed with LiPF3(CF3CF2)3 [J].
Aravindan, V. ;
Vickraman, P. .
EUROPEAN POLYMER JOURNAL, 2007, 43 (12) :5121-5127
[2]  
ARAVINDAN V, 2008, THESIS GANDHIGRAM RU
[3]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[4]   Battery separators [J].
Arora, P ;
Zhang, ZM .
CHEMICAL REVIEWS, 2004, 104 (10) :4419-4462
[5]   An electrospun poly(vinylidene fluoride) nanofibrous membrane and its battery applications [J].
Choi, SW ;
Jo, SM ;
Lee, WS ;
Kim, YR .
ADVANCED MATERIALS, 2003, 15 (23) :2027-2032
[6]   Role of the ceramic fillers in enhancing the transport properties of composite polymer electrolytes [J].
Croce, F ;
Persi, L ;
Scrosati, B ;
Serraino-Fiory, F ;
Plichta, E ;
Hendrickson, MA .
ELECTROCHIMICA ACTA, 2001, 46 (16) :2457-2461
[7]   Characterization of poly(vinylidenefluoride-co-hexafluoropropylene)-based polymer electrolyte filled with rutile TiO2 nanoparticles [J].
Kim, KM ;
Ko, JM ;
Park, NG ;
Ryu, KS ;
Chang, SH .
SOLID STATE IONICS, 2003, 161 (1-2) :121-131
[8]   Characteristics of PVdF-HFP/TiO2 composite membrane electrolytes prepared by phase inversion and conventional casting methods [J].
Kim, Kwang Man ;
Park, Nam-Gyu ;
Ryu, Kwang Sun ;
Chang, Soon Ho .
ELECTROCHIMICA ACTA, 2006, 51 (26) :5636-5644
[9]   Effect of Al2O3 nanoparticles on the electrochemical characteristics of P(VDF-HFP)-based polymer electrolyte [J].
Li, ZH ;
Su, GY ;
Gao, DS ;
Wang, XY ;
Li, XP .
ELECTROCHIMICA ACTA, 2004, 49 (26) :4633-4639
[10]   Influence of TiO2 nano-particles on the transport properties of composite polymer electrolyte for lithium-ion batteries [J].
Lin, CW ;
Hung, CL ;
Venkateswarlu, M ;
Hwang, BJ .
JOURNAL OF POWER SOURCES, 2005, 146 (1-2) :397-401