Electrochemically induced Knoevenagel condensation in solvent- and supporting electrolyte-free conditions

被引：32
作者：
Feroci, Marta
Orsini, Monica
Palombi, Laura
Inesi, Achille
机构：
[1] Univ Roma La Sapienza, Dept ICMMPM, I-00161 Rome, Italy
[2] Univ Salerno, Dept Chem, I-84081 Baronissi, Salerno, Italy
来源：
GREEN CHEMISTRY | 2007年 / 9卷 / 04期
关键词：
D O I：
10.1039/b614483g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Solvent- and supporting electrolyte-free electrochemically induced Knoevenagel condensation of malononitrile with aldehydes or ketones, at 40 degrees C, yields ylidenemalononitriles in high yields.
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收藏
页码：323 / 325
页数：3
相关论文
共 18 条
  • [1] Clean synthesis in water: uncatalysed preparation of ylidenemalononitriles
    Bigi, F
    Conforti, ML
    Maggi, R
    Piccinno, A
    Sartori, G
    [J]. GREEN CHEMISTRY, 2000, 2 (03) : 101 - 103
  • [2] A series of ligands displaying a remarkable agonistic-antagonistic profile at the adenosine A1 receptor
    Chang, LCW
    Künzel, JKVF
    Mulder-Krieger, T
    Spanjersberg, RF
    Roerink, SF
    van den Hout, G
    Beukers, MW
    Brussee, J
    IJzerman, AP
    [J]. JOURNAL OF MEDICINAL CHEMISTRY, 2005, 48 (06) : 2045 - 2053
  • [3] Knoevenagel and aldol condensations catalysed by a new diamino-functionalised mesoporous material
    Choudary, BM
    Kantam, ML
    Sreekanth, P
    Bandopadhyay, T
    Figueras, F
    Tuel, A
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 142 (03) : 361 - 365
  • [4] Uncatalysed Knoevenagel condensation in aqueous medium at room temperature
    Deb, ML
    Bhuyan, PJ
    [J]. TETRAHEDRON LETTERS, 2005, 46 (38) : 6453 - 6456
  • [5] PROPERTIES AND REACTIONS OF YLIDENEMALONONITRILES
    FREEMAN, F
    [J]. CHEMICAL REVIEWS, 1980, 80 (04) : 329 - 350
  • [6] TYRPHOSTINS .1. SYNTHESIS AND BIOLOGICAL-ACTIVITY OF PROTEIN TYROSINE KINASE INHIBITORS
    GAZIT, A
    YAISH, P
    GILON, C
    LEVITZKI, A
    [J]. JOURNAL OF MEDICINAL CHEMISTRY, 1989, 32 (10) : 2344 - 2352
  • [7] Water mediated uncatalyzed facile synthesis of ylidenenitriles of 4-oxo-(4H)-1-benzopyran-3-carbaldehyde
    Hangarge, RV
    Sonwane, SA
    Jarikote, DV
    Shingare, MS
    [J]. GREEN CHEMISTRY, 2001, 3 (06) : 310 - 312
  • [8] A NEW SYNTHESIS OF TETRACYANOCYCLOPROPANES
    HART, H
    KIM, YC
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (09) : 2784 - &
  • [9] Diastereoselective protonation on radical anions of electron-deficient alkenes via photoinduced electron transfer
    Hayamizu, T
    Maeda, H
    Mizuno, K
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (15) : 4997 - 5004
  • [10] Jones G., 1967, ORGANICREACTIONS, V15, P204, DOI [DOI 10.1002/0471264180.OR015.02, 10.1002/0471264180.or015.02]
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