Coordination Assemblies of CdII with 5-(Ethylthio)-1H-tetrazole and Halide Ions: Synthesis, Structure, and Luminescent Properties

被引：0
|
作者：
Tao Ye [1 ]
Li You [1 ]
Yao Peng-Fei [1 ]
Li Hai-Ye [1 ]
Huang Fu-Ping [1 ]
Bian He-Dong [1 ,2 ]
机构：
[1] Guangxi Normal Univ, Sch Pharm & Chem, State Key Lab Chem & Mol Engn Med Resources, Guilin 541004, Peoples R China
[2] Guangxi Univ Nationalities, Key Lab Dev & Applicat Forest Chem Guangxi, Nanning 530006, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 36卷 / 04期
基金：
中国国家自然科学基金;
关键词：
tetrazole; Cd(II) complex; crystal structure; fluorescence properties; METAL-ORGANIC FRAMEWORKS; MAGNETIC-PROPERTIES; POLYMERS; LIGANDS; BEHAVIOR; ADSORPTION; DIVERSITY; AZIDE; ZN2+;
D O I：
10.14102/j.cnki.0254-5861.2011-1284
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three cadmium(II)-halide complexes with 5-(ethylthio)-1H-tetrazole (Hett) as ligand, namely [Cd7Cl2(ett)12(H2O)2] n (1), [Cd-2(OH) Br(ett)2](n) (2) and [Cd-2(OH) I(ett)(2)](n) (3), have been hydrothermally synthesized and characterized. Complex 1 was synthesized at pH = 7 and exhibits a 3D supramolecular framework, where the adjacent Cd ions form a tetrahedron unit by ett ligands bridge and the tetrahedron units share vertices to connect each other by ett bridges to form a 2D layer architecture, which is further interlinked by mu(2)-Cl to form 3D structures. Complexes 2 and 3 are isostructural, generated at pH = 8.0 similar to 9.0, displaying similar 2D networks via ett ligands and different halide ions (Br- in 2, I- in 3, respectively). In addition, thermal stabilities and luminescent properties of new complexes 1 similar to 3 have been studied.
引用
收藏
页码：640 / 646
页数：7
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