Coordination Assemblies of CdII with 5-(Ethylthio)-1H-tetrazole and Halide Ions: Synthesis, Structure, and Luminescent Properties

被引：0
|
作者：
Tao Ye [1 ]
Li You [1 ]
Yao Peng-Fei [1 ]
Li Hai-Ye [1 ]
Huang Fu-Ping [1 ]
Bian He-Dong [1 ,2 ]
机构：
[1] Guangxi Normal Univ, Sch Pharm & Chem, State Key Lab Chem & Mol Engn Med Resources, Guilin 541004, Peoples R China
[2] Guangxi Univ Nationalities, Key Lab Dev & Applicat Forest Chem Guangxi, Nanning 530006, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 36卷 / 04期
基金：
中国国家自然科学基金;
关键词：
tetrazole; Cd(II) complex; crystal structure; fluorescence properties; METAL-ORGANIC FRAMEWORKS; MAGNETIC-PROPERTIES; POLYMERS; LIGANDS; BEHAVIOR; ADSORPTION; DIVERSITY; AZIDE; ZN2+;
D O I：
10.14102/j.cnki.0254-5861.2011-1284
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three cadmium(II)-halide complexes with 5-(ethylthio)-1H-tetrazole (Hett) as ligand, namely [Cd7Cl2(ett)12(H2O)2] n (1), [Cd-2(OH) Br(ett)2](n) (2) and [Cd-2(OH) I(ett)(2)](n) (3), have been hydrothermally synthesized and characterized. Complex 1 was synthesized at pH = 7 and exhibits a 3D supramolecular framework, where the adjacent Cd ions form a tetrahedron unit by ett ligands bridge and the tetrahedron units share vertices to connect each other by ett bridges to form a 2D layer architecture, which is further interlinked by mu(2)-Cl to form 3D structures. Complexes 2 and 3 are isostructural, generated at pH = 8.0 similar to 9.0, displaying similar 2D networks via ett ligands and different halide ions (Br- in 2, I- in 3, respectively). In addition, thermal stabilities and luminescent properties of new complexes 1 similar to 3 have been studied.
引用
收藏
页码：640 / 646
页数：7
相关论文
共 50 条
  • [21] Cobalt(II) and Copper(II) Complexes with New Ditopic Ligand 5-(2-(1H-Tetrazol-1-yl)phenyl)-1H-tetrazole: Synthesis and Properties
    Lavrenova, L. G.
    Grigor'ev, E. Yu.
    Komarov, V. Yu.
    Glinskaya, L. A.
    Lavrov, A. N.
    Grigor'ev, Yu. V.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2023, 49 (02) : 86 - 96
  • [22] Zinc(II) coordination architectures based on 5-(1H-tetrazol-1-yl)-isophthalic acid: Synthesis, structures and luminescent properties
    Zhang, Shu-Ming
    Wang, Gui-Xiang
    Guo, Peng
    Chen, Yu-Huan
    CHINESE CHEMICAL LETTERS, 2015, 26 (09) : 1079 - 1084
  • [23] Syntheses, structures, and fluorescent properties of two new Zn(II) coordination polymers containing 2-((benzoimidazolyl)methyl)-1H-tetrazole
    Liu, Bingtao
    Zhao, Dong
    Li, Ting
    Meng, Xiang-Ru
    JOURNAL OF COORDINATION CHEMISTRY, 2013, 66 (01) : 139 - 151
  • [24] Cobalt(II) and Copper(II) Complexes with New Ditopic Ligand 5-(2-(1H-Tetrazol-1-yl)phenyl)-1H-tetrazole: Synthesis and Properties
    L. G. Lavrenova
    E. Yu. Grigor’ev
    V. Yu. Komarov
    L. A. Glinskaya
    A. N. Lavrov
    Yu. V. Grigor’ev
    Russian Journal of Coordination Chemistry, 2023, 49 : 86 - 96
  • [25] Synthesis, structural diversity and luminescent properties of cadmium(II) coordination assemblies with 2-(2-aminopheny1)-1H-benzimidazole and pseudohalide ions
    Nawrot, I.
    Czerwinska, Katarzyna
    Machura, B.
    Kruszynski, R.
    JOURNAL OF LUMINESCENCE, 2017, 181 : 103 - 113
  • [26] Structural modulation and luminescent properties of four CdII coordination architectures based on 3-(pyridin-4-yl)-5-(pyrazin-2-yl)-1H-1,2,4-triazole and flexible/rigid dicarboxylate ligands
    Xia, Liang
    Dong, Wen-Wen
    Ye, Xiao
    Zhao, Jun
    Li, Dong-Sheng
    JOURNAL OF SOLID STATE CHEMISTRY, 2016, 242 : 120 - 126
  • [27] Coordination Polymers with 2D 3D Interdigitated Arrays Based on 5-(4-(1H-1,2,4-Triazol-1-yl)phenyl)-1H-tetrazole: Syntheses, Structures, and Properties
    Wang, Xi-Chi
    Chen, Yu
    Yuan, Hao
    Yang, Qi
    Zeng, Xiao-Shan
    Qiu, Hai-Jiang
    Xiao, Dong-Rong
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2016, 642 (11-12): : 724 - 729
  • [28] Synthesis, Structure, and Luminescent Property of One Zinc (II) Coordination Polymer Constructed From 1H-Benzoimidazole
    Zhang, Shu Hua
    Zhao, Ru Xia
    Li, Gui
    Zhang, Hai Yang
    Li, He Ping
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2016, 46 (06) : 804 - 808
  • [29] Docking studies and the crystal structure of two tetrazole derivatives: 5-(4-chlorophenyl)-1-{4-(methylsulfonyl)phenyl)-1H-tetrazole and 4-{5-(4-methoxyphenyl)-1H-tetrazol-1-yl}benzenesulfonamide
    Al-Hourani, Baker Jawabrah
    El-Barghouthi, Musa I.
    Mcdonald, Robert
    Al-Awaida, Wajdy
    Wuest, Frank
    JOURNAL OF MOLECULAR STRUCTURE, 2015, 1101 : 21 - 27
  • [30] A Novel Zinc(II)-Organic Coordination Framework Involving in situ Tetrazole Ligand Synthesis: Crystal Structure and Luminescent Properties
    Sun, Lin
    Li, Gui-Zhu
    Xu, Mei-Hua
    Li, Xiao-Jian
    Li, Jian-Rong
    Deng, Hong
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2012, 638 (7-8): : 1200 - 1203
12345