Co(OH)2-NiCo2O4 hybrid nanosheets coupled with N-doping reduced graphene oxide as efficient electrocatalysts for Zn-air batteries

被引:7
|
作者
Peng, Xiaomin [1 ]
Zhang, Jinming [1 ]
Cen, Tianlun [1 ]
Ye, Zhifeng [1 ]
Liu, Yiyi [1 ]
Yuan, Dingsheng [1 ]
机构
[1] Jinan Univ, Sch Chem & Mat Sci, Guangzhou 510632, Peoples R China
基金
中国国家自然科学基金;
关键词
Co(OH)(2)-NiCo2O4 hybrid; N-doping reduced graphene oxide; Synergetic effect; Oxygen catalysts; Zn-air battery; OXYGEN REDUCTION REACTION; DOPED CARBON; EVOLUTION; CATALYSTS; PYROLYSIS;
D O I
10.1016/j.jallcom.2021.159441
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
2-dimensional Co(OH)(2)-NiCo2O4 hybrid nanosheets coupled with N-doping reduced graphene oxide (N-RGO) have been prepared by a facile two-step hydrothermal method for exploring the cost-effective and durable bifunctional oxygen electrocatalysts of Zn-air batteries. Co(OH)(2)-NiCo2O4/N-RGO exhibits the excellent catalytic activity for ORR with a positive half-wave potential of 0.80 V vs. RHE in 0.1 M KOH. And the assembled rechargeable Zn-air battery achieves a high open-circuit voltage of 1.485 V, a large peak power density of 99 mW cm(-2), and a remarkable cycle life of over 180 h. This work offers an inspiration to obtain efficient electrocatalysts for sustainable energy devices. (C) 2021 Elsevier B.V. All rights reserved.
引用
收藏
页数:8
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