Solubility determination and correlation for spirotetramat in different solvent systems at T=278.15-318.15 K

被引：7
作者：
Yuan, Mengjie [1 ]
Yuan, Peiquan [1 ]
Liu, Baoshu [1 ]
Sun, Hua [1 ]
机构：
[1] Hebei Univ Sci & Technol, Coll Chem & Pharmaceut Engn, Shijiazhuang 050018, Hebei, Peoples R China
来源：
JOURNAL OF CHEMICAL THERMODYNAMICS | 2022年 / 173卷
关键词：
Spirotetramat; Solubility; Thermodynamic model; Solvent effect; DISODIUM 5'-GUANYLATE HEPTAHYDRATE; WATER; MIXTURES; ETHANOL; METHANOL; NRTL;
D O I：
10.1016/j.jct.2022.106854
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The solubility of spirotetramat in four binary solvents (methanol + water, ethanol + water, isopropanol + water, acetone + water) were studied by laser monitoring observation technique. The solubility data of spirotetramat in binary mixed solvents were subsequently fitted by the modified Apelblat model, lambda h model, Van't Hoff model, Jouyban-Acree model and NRTL model. The results showed that Apelblat model and Van't Hoff model were more suitable for fitting the solubility data. Furthermore, the effects of the solute-solvent intermolecular interactions on the solubility were analyzed using the KAT-LSER model. The results showed that the dipolar/polarizability of the solvent had the greatest influence on the solubility of spirotetramat.
引用
收藏
页数：9
相关论文
共 37 条
  • [1] Solubility and thermodynamic function of vitamin D3 in different mono solvents
    Almarri, Fahad
    Haq, Nazrul
    Alanazi, Fars K.
    Mohsin, Kazi
    Alsarra, Ibrahim A.
    Aleanizy, Fadilah S.
    Shakeel, Faiyaz
    [J]. JOURNAL OF MOLECULAR LIQUIDS, 2017, 229 : 477 - 481
  • [2] Movento®, an innovative ambimobile insecticide for sucking insect pest control in agriculture: Biological profile and field performance
    Brueck, Ernst
    Elbert, Alfred
    Fischer, Reiner
    Krueger, Stephen
    Kuehnhold, Juergen
    Klueken, A. Michael
    Nauen, Ralf
    Niebes, Jean-Francois
    Reckmann, Udo
    Schnorbach, Hans-Juergen
    Steffens, Robert
    van Waetermeulen, Xavier
    [J]. CROP PROTECTION, 2009, 28 (10) : 838 - 844
  • [3] Solubility determination and analysis of methimazole in different solvent systems at T=278.15-323.15 K
    Chen, Chen
    Zhou, Peng
    Wang, Rensong
    Zhu, Fu
    Sun, Wei
    Shen, Weiliang
    Xu, Hanhan
    Hu, Guoxing
    Hu, Yonghong
    Yang, Wenge
    [J]. JOURNAL OF MOLECULAR LIQUIDS, 2021, 342
  • [4] Protein purification with nanoparticle-enhanced crystallisation
    Chen, Wenqian
    Cheng, Thomas N. H.
    Khaw, Liang Fa
    Li, Xiaoyu
    Yang, Huaiyu
    Ouyang, Jinbo
    Heng, Jerry Y. Y.
    [J]. SEPARATION AND PURIFICATION TECHNOLOGY, 2021, 255
  • [5] Solubility determination and dissolution thermodynamic properties of dodecanedioic acid in binary-mixed solvents from T = (288.15-328.15) K
    Cheng, Shuo
    Bao, Yu
    Cui, Yue
    Wang, Jingtao
    [J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 2022, 166
  • [6] One-parameter modified nonrandom two-liquid (NRTL) activity coefficient model
    Gebreyohannes, Solomon
    Neely, Brian J.
    Gasem, Khaled A. M.
    [J]. FLUID PHASE EQUILIBRIA, 2014, 379 : 196 - 205
  • [7] Crystallization of vanillin from kraft lignin oxidation
    Gomes, E. D.
    Rodrigues, A. E.
    [J]. SEPARATION AND PURIFICATION TECHNOLOGY, 2020, 247
  • [8] Solvent effect and solubility modeling of rebamipide in twelve solvents at different temperatures
    Ha, Eun-Sol
    Lee, Seon-Kwang
    Jeong, Ji-Su
    Sim, Woo-Yong
    Yang, Jun-Il
    Kim, Jeong-Soo
    Kim, Min-Soo
    [J]. JOURNAL OF MOLECULAR LIQUIDS, 2019, 288
  • [9] Solubility of L-tyrosine in aqueous solutions of methanol, ethanol, n-propanol and dimethyl sulfoxide: Experimental determination and preferential solvation analysis
    He, Qingchun
    Cong, Yang
    Zheng, Min
    Farajtabar, Ali
    Zhao, Hongkun
    [J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 2018, 124 : 123 - 132
  • [10] Measurement and correlation of solubility, Hansen solubility parameters and thermodynamic behavior of Clozapine in eleven mono-solvents
    Huang, Wei
    Wang, Hairong
    Li, Chunrong
    Wen, Ting
    Xu, Jikun
    Ouyang, Jinbo
    Zhang, Chuntao
    [J]. JOURNAL OF MOLECULAR LIQUIDS, 2021, 333
1234