Recyclable and Magnetically Functionalized Metal-Organic Framework Catalyst: IL/Fe3O4@HKUST-1 for the Cycloaddition Reaction of CO2 with Epoxides

被引：32
|
作者：
Wang, Tongtong [1 ]
Song, Xuedan [1 ]
Xu, Hailong [1 ]
Chen, Miaomiao [1 ]
Zhang, Jie [2 ]
Ji, Min [1 ]
机构：
[1] Dalian Univ Technol, Fac Chem Environm & Biol Sci & Technol, Sch Chem, Dalian 116023, Peoples R China
[2] Beijing Inst Technol, Sch Chem & Chem Engn, MOE Key Lab Cluster Sci, Beijing Key Lab Photoelect Electrophoton Convers, Beijing 102488, Peoples R China
来源：
ACS APPLIED MATERIALS & INTERFACES | 2021年 / 13卷 / 19期
基金：
中国国家自然科学基金;
关键词：
CO2; metal-organic frameworks (MOFs); magnetic material; nanocomposite; heterogeneous catalysis; recyclable catalyst; CARBON-DIOXIDE; IONIC LIQUID; ADSORPTION PROPERTIES; PROPYLENE CARBONATE; FACILE FABRICATION; CYCLIC CARBONATES; HIGHLY EFFICIENT; CONVERSION; CAPTURE; COMPOSITES;
D O I：
10.1021/acsami.1c03345
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
A recyclable and magnetic nanocomposite catalyst (IL/Fe3O4@HKUST-1) was synthesized via grafting ionic liquid (IL) [AEMIm]BF4 into magnetically functionalized metal-organic framework Fe3O4@HKUST-1 in a water-ethanol media. The properties of IL/Fe3O4@HKUST-1 were fully characterized by powder X-ray diffraction, electron microscopy, Fourier-transform infrared spectroscopy, nitrogen adsorption-desorption, density-functional theory, and a magnetic property measurement system. IL/Fe3O4@HKUST-1 showed high activity in the solvent-free cycloaddition of CO2 with epoxides under mild conditions. Furthermore, the catalyst can be easily separated from the reaction mixture, and the recycled catalyst maintained high performance for several cycles. The synergistic effect of the Lewis acid and base sites in IL/Fe3O4@HKUST-1 contributes to its greater reactivity than individual IL or HKUST-1.
引用
收藏
页码：22836 / 22844
页数：9
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