Luminescence sensing of weakly-hydrated anions in aqueous solution by self-assembled europium(III) complexes

被引:18
|
作者
Sagami, Takuya [1 ]
Tahara, Yuhei O. [2 ,3 ]
Miyata, Makoto [2 ]
Miyake, Hiroyuki [1 ]
Shinoda, Satoshi [1 ]
机构
[1] Osaka City Univ, Dept Chem, Grad Sch Sci, Osaka 5588585, Japan
[2] Osaka City Univ, Grad Sch Sci, Dept Biol, Osaka 5588585, Japan
[3] Osaka City Univ, OCU Adv Res Inst Nat Sci & Technol OCARINA, Osaka 5588585, Japan
关键词
PERCHLORATE ION; METAL-COMPLEXES; WATER; QUANTITATION; RECOGNITION; REMOVAL; CATIONS; STATE;
D O I
10.1039/c7cc00477j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Self-assembled europium(III) complexes produced dispersed nanoparticles with diameters of about 4-8 nm, which exhibited long-lived luminescence in a 20 wt% EtOH-H2O solution. The complexes could sense weakly hydrated anions, such as perchlorate, by a change in luminescence intensity using an anion displacement method.
引用
收藏
页码:3967 / 3970
页数:4
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