PdII-Catalyzed Highly Selective Arylation of Allyl Esters via C-H Functionalization of Unreactive Arenes with Retention of the Traditional Leaving Group

被引：39
|
作者：
Pan, Delin [2 ]
Yu, Miao [1 ]
Chen, Wei [3 ]
Jiao, Ning [2 ]
机构：
[1] Chinese Peoples Liberat Army Gen Hosp, Dept Radiol, Beijing 100853, Peoples R China
[2] Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
[3] Chinese PLA Postgrad Med Sch, Beijing 100853, Peoples R China
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2010年 / 5卷 / 05期
基金：
美国国家科学基金会;
关键词：
allylic compounds; heck reaction; palladium; regioselectivity; silver; OXIDATIVE HECK REACTIONS; ARYLBORONIC ACIDS; BASE-FREE; ORGANOMETALLIC CHEMISTRY; PALLADIUM(II) CATALYSIS; COUPLING REACTIONS; ROOM-TEMPERATURE; BOND FORMATION; ARYL HALIDES; OLEFINS;
D O I：
10.1002/asia.200900558
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A highly selective Fujiwara-Moritani oxidative Heck reaction of allyl esters with unreactive arenes via C - H bond activation was developed, in which -H elimination is highly chemo-, regio- and stereoselective. Moreover, even electron-deficient arenes are tolerated in this type of C - H activation. © 2010 Wiley-VCH Verlag GmbH © Co. KGaA, Weinheim.
引用
收藏
页码：1090 / 1093
页数：4
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