Charge-transfer salts containing cyclic perfluorinated anions

被引：1
|
作者：
Briscoe, MW
Chambers, RD
Clegg, W
Gibson, VC
Mullins, SJ
Vaughan, JFS
机构：
[1] UNIV DURHAM,DEPT CHEM,SCI LABS,DURHAM DH1 3LE,ENGLAND
[2] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1996年 / 76卷 / 01期
基金：
英国工程与自然科学研究理事会;
关键词：
charge-transfer salts; perfluorinated cyclic alkenes; crystal structure; cyclic voltammetry;
D O I：
10.1016/0022-1139(95)03335-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Perfluorobicyclopentenyl (1a) and -butenyl (2a) react with decamethylferrocene (3), to give charge-transfer salts 4 and 5, respectively; perfluorohexakis (trifluoromethyl) cyclo-pentadiene (6) forms a salt (8) containing the C-5(CF3)(5) anion, Crystal structures of the salts 4 and 5 have been determined; both contain centrosymmetric trans-diene radical anions.
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页码：1 / 2
页数：2
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