Highly selective aerobic oxidation of alcohols to aldehydes over a new Cu(II)-based metal-organic framework with mixed linkers

被引：34

作者：

Chen, Sheng-Chun ^{[1
]}

Lu, Sheng-Nan ^{[1
]}

Tian, Feng ^{[2
]}

Li, Nan ^{[1
]}

Qian, Han-Yu ^{[3
]}

Cui, Ai-Jun ^{[1
]}

He, Ming-Yang ^{[1
,2
]}

Chen, Qun ^{[1
]}

机构：

[1] Changzhou Univ, Sch Petrochem Engn, Key Lab Fine Petrochem Technol, Changzhou 213164, Peoples R China

[2] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China

[3] China Pharmaceut Univ, Sch Pharm, Nanjing 211198, Jiangsu, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2017年 / 95卷

基金：

中国国家自然科学基金;

关键词：

Cu(II) MOF; Aerobic oxidation; Alcohol; Heterogeneous catalysis; Aldehyde; HETEROGENEOUS CATALYST; MOLECULAR-OXYGEN; SWERN OXIDATION; NANOPARTICLES; NETWORKS;

D O I：

10.1016/j.catcom.2017.02.024

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new Cu(II)-based metal-organic framework {[Cu-2(1,2-BDC)(2)(Fbtx)(2)]center dot 3H(2)O}(n) (denoted as Cu-FMOF, CCDC-1519440, 1,2-BDC = 1,2-benzenedicarboxylate, Fbtx = 1,4-bis(1,2,4-triazole-1-ylmethyl)-2,3,5,6-tetrafluorobenenze) was hydrothermally synthesized and structurally characterized. The Cu-FMOF exhibits a 3D 4-connected coordination framework with the extremely rare (6(5).8)-hxg-d-4-P2/c topology. Using air as the oxidant, the crystalline Cu-FMOF could be used as a highly efficient heterogeneous catalyst for the TEMPO assisted oxidation of alcohols to aldehydes. Furthermore, the Cu-FMOF catalyst could be easily recovered and reused for several times without a significant loss of catalytic activity or structural deterioration. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：6 / 11

页数：6

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