Capture of heliophobic atoms by 4He nanodroplets: the case of cesium

被引:23
作者
Leal, Antonio [1 ,2 ]
Mateo, David [3 ]
Hernando, Alberto [4 ]
Pi, Marti [1 ,2 ]
Barranco, Manuel [1 ,2 ]
机构
[1] Univ Barcelona, Dept ECM, Fac Fis, Barcelona 08028, Spain
[2] Univ Barcelona, IN2UB, Barcelona 08028, Spain
[3] Calif State Univ Northridge, Dept Chem & Biochem, Northridge, CA 91330 USA
[4] Swiss Fed Inst Technol Lausanne EPFL, Lab Theoret Phys Chem, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland
关键词
SUPERFLUID-HELIUM; LIQUID-HELIUM; ALKALI ATOMS; DYNAMICS; SPECTROSCOPY; DESORPTION; POTENTIALS; SCATTERING; MOLECULES; CLUSTERS;
D O I
10.1039/c4cp03297g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Within Density Functional Theory (DFT), we address the capture of a Cs atom by a superfluid helium nanodroplet using models of different complexity. In the simplest model, the Cs-droplet potential is obtained in two extreme approximations, namely the sudden approximation in which one assumes that the density of the droplet is not relaxed as Cs approaches it, and the adiabatic approximation in which one assumes that it does. Next, a more complex approach in which the collision is described within a time-dependent DFT approach is employed. Depending on the energy and impact parameter of the impinging Cs atom, a rich variety of dynamical phenomena appears that is discussed in some detail.
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页码:23206 / 23213
页数:8
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