Low Density Polyethylene (LDPE) blends based on Poly(3-Hydroxi-Butyrate) (PHB) and Guar Gum (GG) biodegradable polymers

被引:9
作者
Guimaraes Rocha, Marisa Cristina [1 ]
da Costa Moraes, Lorena Rodrigues [1 ]
机构
[1] Univ Estado Rio de Janeiro UERJ, Inst Politecn, Nova Friburgo, RJ, Brazil
来源
POLIMEROS-CIENCIA E TECNOLOGIA | 2015年 / 25卷 / 01期
关键词
blends; guar gum; low density polyethylene; mechanical properties; poly (3-hydroxi-butyrate); STARCH; FILMS;
D O I
10.1590/0104-1428.1495
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
LDPE blends based on PHB and GG biodegradable polymers were prepared by melt mixing in a twin screw extruder. The mechanical properties of the materials were evaluated. Preliminary information about the biodegradation behavior of the specimens was obtained by visual observation of samples removed from the simulated soil in 90 days. The results indicated that LDPE/PHB blends may be used for designing LDPE based materials with increased susceptibility to degradation, if elongation at break and impact properties are not determinant factors of their performance. LDPE based materials on GG present values of flexural and mechanical strength lower than those of LDPE/PHB blends. LDPE/PHB/GG blends exhibit unsatisfactory properties. Apparently, the effect of addition of GG to LDPE on the biodegradation behavior of LDPE/GG blends was less intense than the effect caused by addition of PHB to the blends. Similar observation has occurred with the partial replacement of GG by PHB in the ternary blends.
引用
收藏
页码:42 / 48
页数:7
相关论文
共 24 条
[1]  
Arkatkar A., 2009, The Open Environmental Engineering Journal, V2, P68, DOI 10.2174/1874829500902010068
[2]   Biodegradable films made from low-density polyethylene (LDPE), rice starch and potato starch for food packaging applications: Part 1 [J].
Arvanitoyannis, I ;
Biliaderis, CG ;
Ogawa, H ;
Kawasaki, N .
CARBOHYDRATE POLYMERS, 1998, 36 (2-3) :89-104
[3]   Review - Properties of blends and composites based on poly(3-hydroxy)butyrate (PHB) and poly(3-hydroxybutyrate-hydroxyvalerate) (PHBV) copolymers [J].
Avella, M ;
Martuscelli, E ;
Raimo, M .
JOURNAL OF MATERIALS SCIENCE, 2000, 35 (03) :523-545
[4]  
Azero E. G., 1999, POLIMEROS, V9, P54
[5]  
Banegas R. S., 2009, AN 32 REUN AN SOC BR
[6]   Preparation, Characterization and Properties of Films Obtained from Cross-linked Guar Gum [J].
Banegas, Rodrigo S. ;
Zornio, Clarice F. ;
Borges, Adriana de M. G. ;
Porto, Ledilege C. ;
Soldi, Valdir .
POLIMEROS-CIENCIA E TECNOLOGIA, 2013, 23 (02) :182-188
[7]  
Burlein G. A. D., 2010, THESIS STATE U RIO D
[8]   Biodegradable polymers [J].
Chandra, R ;
Rustgi, R .
PROGRESS IN POLYMER SCIENCE, 1998, 23 (07) :1273-1335
[9]  
Coutinho Fernanda M. B., 2003, Polímeros, V13, P01
[10]  
Gupta A.P., 2012, Der Chimica Sinica, V3, P1191