Recent advances in transition metal diborane(6), diborane(4) and diborene(2) chemistry

Diborane(4) and diborane(6) molecules are demanding renewed interest due to their varied reactivity towards diverse substrates. The chemistry of molecules comprising electron-precise B-B bonds has witnessed swift developments in the recent years. In spite of the continuous interest and extensive efforts in the synthesis of diborane compounds, the formation of boron-boron bonds is still difficult and uncontrolled. On the other hand, the diborene molecules (R-B=B-R'; R, R' = H, phosphine, amine, NHC etc), are also of significant interest owing to their ability to regulate the property of biradicals by changing the substituents of the parent diborene(2), HB=BH. In addition, transition metal diborene species exhibit fascinating photo-physical properties. In this review, we have delivered a background of B-B bond formation and a synopsis of the latest developments in the synthesis of boron-boron single and multiple bonds. The reactivity of diborane/diborene complexes towards various transition metals has also been discussed in detail. (C) 2019 Elsevier B.V. All rights reserved.