Review: Mixed- valent metallodendrimers: design and functions

被引:13
作者
Astruc, Didier [1 ]
Rapakousiou, Amalia [1 ]
Wang, Yanlan [1 ]
Djeda, Rodrigue [1 ]
Diallo, Abdou [1 ]
Ruiz, Jaime [1 ]
Ornelas, Catia [1 ]
机构
[1] Univ Bordeaux, ISM, CNR, UMR 5255, Talence, France
关键词
Dendrimer; Ferrocene; Iron complexes; Mixed valence; Redox; Molecular recognition; Electrostatic effect; ORGANOMETALLIC ELECTRON-RESERVOIRS; ATTACHED GOLD NANOPARTICLES; FERROCENYL DENDRIMERS; BIOMEDICAL APPLICATIONS; MOLECULAR ELECTRONICS; DELTA-E-1/2; VALUES; TRANSFER CHEMISTRY; REDOX BEHAVIOR; COMPLEXES; CATALYSIS;
D O I
10.1080/00958972.2014.939648
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Various types of mixed-valent metallodendrimers and star-shaped macromolecules containing ferrocenyl, biferrocenyl, or other redox-robust iron groups with rigid or flexible tethers of short and long lengths mostly studied in the authors' laboratory including the class type in terms of Robin-Day classification and their functions including electrode modification, sensing, and nanoparticle templates are discussed in this mini review.
引用
收藏
页码:3809 / 3821
页数:13
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