Grafting of Poly(poly(ethylene glycol) methacrylate) onto Halloysite Nanotubes via Surface-Initiated Atom Transfer Radical Polymerization

被引:1
作者
Long Giang Bach [1 ]
Trinh Duy Nguyen [1 ]
Nguyen Thi Thuong [1 ]
Ho Thi Thanh Van [2 ]
Dai Hai Nguyen [3 ]
Lim, Kwon Taek [4 ]
机构
[1] Nguyen Tat Thanh Univ, Nguyen Tat Thanh Inst Hitechnol, Ho Chi Minh City 702000, Vietnam
[2] Hochiminh City Univ Nat Resources & Environm, Ho Chi Minh City 705000, Vietnam
[3] Vietnam Acad Sci & Technol, Inst Appl Mat Sci, Hanoi 701000, Vietnam
[4] Pukyong Natl Univ, Dept Imaging Syst Engn, Busan 608737, South Korea
关键词
Halloysite Nanotubes; Poly(poly(ethylene glycol) methacrylate); Atom Transfer Radical Polymerization; DRUG-DELIVERY; HYDROGELS; RELEASE; DESIGN; FILMS; ATRP;
D O I
10.1166/jnn.2019.15923
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A synthetic strategy for the functionalization of halloysite nanotubes (HNTs) with poly(poly(ethylene glycol) methacrylate) (PPEGMA) via surface-initiated atom transfer radical polymerization (SIATRP). The covalent immobilization of PPEGMA was confirmed by FT-IR analysis. The preparation of the nanohybrids was further evidenced by the XPS and EDX studies. The morphologies of functionalized HNTs were investigated by FE-SEM analysis. TGA results suggested that the nanohybrids can be used in high temperature applications. Thus, this newly developed surface functionalization protocol offers the tailoring of the HNTs surface with wide functionalities and is potentially useful to the biomedical applications.
引用
收藏
页码:927 / 931
页数:5
相关论文
共 14 条
[1]   Poly(ethylene glycol) methacrylate/dimethacrylate hydrogels for controlled release of hydrophobic drugs [J].
DiRamio, JA ;
Kisaalita, WS ;
Majetich, GF ;
Shimkus, JM .
BIOTECHNOLOGY PROGRESS, 2005, 21 (04) :1281-1288
[2]   New polymer-halloysite hybrid materials-potential controlled drug release system [J].
Ghebaur, Adi ;
Garea, Sorina A. ;
Iovu, Horia .
INTERNATIONAL JOURNAL OF PHARMACEUTICS, 2012, 436 (1-2) :568-573
[3]   Water-assisted extrusion as a novel processing route to prepare polypropylene/halloysite nanotube nanocomposites: Structure and properties [J].
Lecouvet, B. ;
Sclavons, M. ;
Bourbigot, S. ;
Devaux, J. ;
Bailly, C. .
POLYMER, 2011, 52 (19) :4284-4295
[4]   Functionalization of poly(oligo(ethylene glycol)methacrylate) films on gold and Si/SiO2 for immobilization of proteins and cells:: SPR and QCM studies [J].
Lee, Bong Soo ;
Chi, Young Shik ;
Lee, Kyung-Bok ;
Kim, Yang-Gyun ;
Choi, Insung S. .
BIOMACROMOLECULES, 2007, 8 (12) :3922-3929
[5]   Iron oxide-based superparamagnetic polymeric nanomaterials: Design, preparation, and biomedical application [J].
Oh, Jung Kwon ;
Park, Jong Myung .
PROGRESS IN POLYMER SCIENCE, 2011, 36 (01) :168-189
[6]   Poly(ethylene glycol)-containing hydrogels in drug delivery [J].
Peppas, NA ;
Keys, KB ;
Torres-Lugo, M ;
Lowman, AM .
JOURNAL OF CONTROLLED RELEASE, 1999, 62 (1-2) :81-87
[7]  
Qi R., 2010, J MATER CHEM, V20, P106
[8]   Single-Monomer Formulation of Polymerized Polyethylene Glycol Diacrylate as a Nonadsorptive Material for Microfluidics [J].
Rogers, Chad I. ;
Pagaduan, Jayson V. ;
Nordin, Gregory P. ;
Woolley, Adam T. .
ANALYTICAL CHEMISTRY, 2011, 83 (16) :6418-6425
[9]   Poly(ethylene glycol)-stabilized silver nanoparticles for bioanalytical applications of SERS spectroscopy [J].
Shkilnyy, Andriy ;
Souce, Martin ;
Dubois, Pierre ;
Warmont, Fabienne ;
Saboungi, Marie-Louise ;
Chourpa, Igor .
ANALYST, 2009, 134 (09) :1868-1872
[10]   ATRP in the design of functional materials for biomedical applications [J].
Siegwart, Daniel J. ;
Oh, Jung Kwon ;
Matyjaszewski, Krzysztof .
PROGRESS IN POLYMER SCIENCE, 2012, 37 (01) :18-37