Au/α-Fe2O3 catalyst for water-gas shift reaction prepared by deposition-precipitation

被引:137
作者
Andreeva, D
Tabakova, T
Idakiev, V
Christov, P
Giovanoli, R
机构
[1] Bulgarian Acad Sci, Inst Catalysis, BU-1113 Sofia, Bulgaria
[2] Univ Bern, CH-3000 Bern 9, Switzerland
关键词
Au/alpha-Fe2O3; preparation; WGS reaction;
D O I
10.1016/S0926-860X(97)00302-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A modified version of the preparation methods for the synthesis of highly-active Au/alpha-Fe2O3 catalysts for WGS reaction has been proposed. The results obtained show that gold dispersion is highly preserved and prevents cluster formation. On the other hand, a major part of gold remains on the surface, thus being accessible to catalysis. As a result of the preparation technique, it seems that the interaction between gold and support is weaker and, likely, more favourable for catalysis. This study demonstrates that a specific approach to preparation of catalysts of optimum structure and texture is crucial for high-catalytic activity. (C) 1998 Elsevier Science B.V.
引用
收藏
页码:9 / 14
页数:6
相关论文
共 9 条
  • [1] Low-temperature water-gas shift reaction on Au/alpha-Fe2O3 catalyst
    Andreeva, D
    Idakiev, V
    Tabakova, T
    Andreev, A
    Giovanoli, R
    [J]. APPLIED CATALYSIS A-GENERAL, 1996, 134 (02) : 275 - 283
  • [2] ANDREEVA D, 1995, J CATAL, V157, P354
  • [3] Surface characterization study of Au/alpha-Fe2O3 and Au/Co3O4 low-temperature CO oxidation catalysts
    Epling, WS
    Hoflund, GB
    Weaver, JF
    Tsubota, S
    Haruta, M
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (23) : 9929 - 9934
  • [4] LOW-TEMPERATURE OXIDATION OF CO OVER GOLD SUPPORTED ON TIO2, ALPHA-FE2O3, AND CO3O4
    HARUTA, M
    TSUBOTA, S
    KOBAYASHI, T
    KAGEYAMA, H
    GENET, MJ
    DELMON, B
    [J]. JOURNAL OF CATALYSIS, 1993, 144 (01) : 175 - 192
  • [5] Haruta M., 1988, SUCCESSFUL DESIGN CA, P33
  • [6] HARUTA M, 1988, P 9 INT C CAT CALG O, V2, P1206
  • [7] X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF IRON-OXIDES
    MCINTYRE, NS
    ZETARUK, DG
    [J]. ANALYTICAL CHEMISTRY, 1977, 49 (11) : 1521 - 1529
  • [8] X-RAY PHOTOELECTRON-SPECTROSCOPY OF CO3O4, FE3O4, MN3O4 AND RELATED COMPOUNDS
    OKU, M
    HIROKAWA, K
    [J]. JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1976, 8 (06) : 475 - 481
  • [9] TSUBOTA S, 1995, PREPARATION CATALYST, V6, P227