Au/α-Fe2O3 catalyst for water-gas shift reaction prepared by deposition-precipitation

被引:137
作者
Andreeva, D
Tabakova, T
Idakiev, V
Christov, P
Giovanoli, R
机构
[1] Bulgarian Acad Sci, Inst Catalysis, BU-1113 Sofia, Bulgaria
[2] Univ Bern, CH-3000 Bern 9, Switzerland
关键词
Au/alpha-Fe2O3; preparation; WGS reaction;
D O I
10.1016/S0926-860X(97)00302-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A modified version of the preparation methods for the synthesis of highly-active Au/alpha-Fe2O3 catalysts for WGS reaction has been proposed. The results obtained show that gold dispersion is highly preserved and prevents cluster formation. On the other hand, a major part of gold remains on the surface, thus being accessible to catalysis. As a result of the preparation technique, it seems that the interaction between gold and support is weaker and, likely, more favourable for catalysis. This study demonstrates that a specific approach to preparation of catalysts of optimum structure and texture is crucial for high-catalytic activity. (C) 1998 Elsevier Science B.V.
引用
收藏
页码:9 / 14
页数:6
相关论文
共 9 条
[1]   Low-temperature water-gas shift reaction on Au/alpha-Fe2O3 catalyst [J].
Andreeva, D ;
Idakiev, V ;
Tabakova, T ;
Andreev, A ;
Giovanoli, R .
APPLIED CATALYSIS A-GENERAL, 1996, 134 (02) :275-283
[2]  
ANDREEVA D, 1995, J CATAL, V157, P354
[3]   Surface characterization study of Au/alpha-Fe2O3 and Au/Co3O4 low-temperature CO oxidation catalysts [J].
Epling, WS ;
Hoflund, GB ;
Weaver, JF ;
Tsubota, S ;
Haruta, M .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (23) :9929-9934
[4]   LOW-TEMPERATURE OXIDATION OF CO OVER GOLD SUPPORTED ON TIO2, ALPHA-FE2O3, AND CO3O4 [J].
HARUTA, M ;
TSUBOTA, S ;
KOBAYASHI, T ;
KAGEYAMA, H ;
GENET, MJ ;
DELMON, B .
JOURNAL OF CATALYSIS, 1993, 144 (01) :175-192
[5]  
Haruta M., 1988, SUCCESSFUL DESIGN CA, P33
[6]  
HARUTA M, 1988, P 9 INT C CAT CALG O, V2, P1206
[7]   X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF IRON-OXIDES [J].
MCINTYRE, NS ;
ZETARUK, DG .
ANALYTICAL CHEMISTRY, 1977, 49 (11) :1521-1529
[8]   X-RAY PHOTOELECTRON-SPECTROSCOPY OF CO3O4, FE3O4, MN3O4 AND RELATED COMPOUNDS [J].
OKU, M ;
HIROKAWA, K .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1976, 8 (06) :475-481
[9]  
TSUBOTA S, 1995, PREPARATION CATALYST, V6, P227