Synthesis of chiral quaternary fluorinated cyclic sulfamidates via palladium-catalyzed arylation with arylboronic acids

被引：8

作者：

Chen, Mu-Wang ^{[1
,2
]}

Mao, Xuechun ^{[1
,2
]}

Ji, Yue ^{[3
]}

Yuan, Jianjun ^{[1
,2
]}

Deng, Zhihong ^{[1
,2
]}

Peng, Yiyuan ^{[1
,2
]}

机构：

[1] Minist Educ, Jiangxi Prov Key Lab Green Chem, Key Lab Funct Small Organ Mol, Nanchang 330022, Jiangxi, Peoples R China

[2] Jiangxi Normal Univ, Nanchang 330022, Jiangxi, Peoples R China

[3] Xian Shiyou Univ, Coll Chem & Chem Engn, Xian 710065, Shaanxi, Peoples R China

来源：

TETRAHEDRON LETTERS | 2019年 / 60卷 / 48期

基金：

中国国家自然科学基金;

关键词：

Asymmetric-addition; Quaternary fluorinated cyclic sulfamidate; Palladium catalyst; Arylboronic acid; PD(II)-CATALYZED ASYMMETRIC ADDITION; C-H AMINATION; ENANTIOSELECTIVE SYNTHESIS; NUCLEOPHILIC ALLYLATION; IMINES; LIGANDS; ACCESS; TRIFLUOROMETHYLATION; CYTOCHROME-P450; HYDRAZONES;

D O I：

10.1016/j.tetlet.2019.151280

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An enantioselective palladium-catalyzed arylation of fluorinated cyclic N-sulfonyl ketimines with arylboronic acids is described. This methodology provides an efficient and convenient route to chiral quaternary fluorinated cyclic sulfamidates in high yields with up to 99% ee. (C) 2019 Elsevier Ltd. All rights reserved.

引用

页数：4

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