Experimental investigations and a simple balance model of a metal hydride reactor

The metal hydride reactor filled with 5 kg of the AB(5)-type (LaFe0.5Mn0.3Ni4.8) alloy was investigated with respect to the hydrogen discharge rates classified using C-rate value, which is discharge of the maximum hydrogen capacity 750 st L within 1 h. The reactor cannot be fully discharged with a constant flow rate, for each temperature of hot water and flow rate there exists a moment of crisis at which the hydrogen flow drops under the constant value. The nominal capacity of the reactor reaches 80% of maximum capacity if sufficient heat transfer is provided. The simple balance model of a metal hydride reactor is developed based on the assumption of uniform temperature and pressure inside a metal hydride bed. The model permits to predict behavior of the metal hydride reactor in different operation regimes, quantitative agreement is obtained for low C-rates (less than 4) and sub-critical modes. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.