Polyelectrolyte multilayers containing photoreactive groups

被引:28
作者
Laschewsky, A [1 ]
Wischerhoff, E [1 ]
Bertrand, P [1 ]
Delcorte, A [1 ]
机构
[1] UNIV CATHOLIQUE LOUVAIN,DEPT MAT & PROC SCI,B-1348 LOUVAIN,BELGIUM
关键词
D O I
10.1002/macp.1997.021981021
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The synthesis of a photocrosslinkable polycation and its use in the assembly of alternating polyelectrolyte multilayers are described. Characterization by UV/VIS spectroscopy and time-of-flight secondary ion mass spectroscopy (ToF-SIMS) reveals the influence of the crosslinking on the physical properties of the build-ups. Remarkably, the assembly of such multilayer structures is not only possible on hydrophilic substrates, but also on apolar poly(propylene). In this case, the crosslinkable polycation turns out to be especially useful to obtain stable, solvent resistant coatings.
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页码:3239 / 3253
页数:15
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